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二氧化硅负载磷钨杂多酸钠光催化降解甲基紫
引用本文:苏爽月,马荣华.二氧化硅负载磷钨杂多酸钠光催化降解甲基紫[J].科技资讯,2009(23):87-88.
作者姓名:苏爽月  马荣华
作者单位:1. 牡丹江师范学院化学系,黑龙江牡丹江,157012
2. 齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔,161006
摘    要:本实验研究了Keggin型杂多化合物Na3PW12O40/SiO2(二氧化硅负载的磷钨杂多酸钠)在紫外光的照射下催化降解有机染料甲基紫的效能。实验结果表明,催化剂用量不同,溶液的初始浓度,酸度不同则降解有机染料的效率不同。催化剂加入量的最佳值为0.09g/L;溶液的初始浓度为2mg/L时,降解的效果最佳;降解最适宜的初始酸度为pH=1。Keggin型杂多化合物Na3PW12O40/SiO2光催化降解甲基紫为一级动力学反应。

关 键 词:杂多化合物  光催化降解  甲基紫

Study on Photocatalytic Degradation of Methyl Violet with Na3PW12O40/SiO2
SU Shuang-yue,MA Rong-hua.Study on Photocatalytic Degradation of Methyl Violet with Na3PW12O40/SiO2[J].Science & Technology Information,2009(23):87-88.
Authors:SU Shuang-yue  MA Rong-hua
Institution:1.Department of Chemistry, Mudanjiang Normal College, Mudanjiang, 157000, China; 2.Department of Chemistry, Qiqihar University, Qiqihar, 161006, China)
Abstract:Study on the efficiency of the Na3PW12O40/SiO2 in the photecatalytic degradation was carried out under different conditions. Methyl violet was used as the aims of degradation and a low pressure mercury lamp was taken as light source (25W). The results show the optimal reaction condions are that the amount of the catalyst is 0.09g/L, the initial concentration of methyl violet solution is 2mg/L and the initial acidity is pH=. The reaction of photocatalytic degradation of methyl violet with Na3PW12O40/SiO2 follows the characteristic first--order reaction kinetics.
Keywords:heteropoly compound  photocatalytic degradation  methyl violet
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