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UV/O3法降解乙酸的影响因素
引用本文:康春莉,唐晓剑,郭平,郭晶,于宏兵.UV/O3法降解乙酸的影响因素[J].吉林大学学报(理学版),2008,46(1):162-165.
作者姓名:康春莉  唐晓剑  郭平  郭晶  于宏兵
作者单位:吉林大学 环境与资源学院, 长春 130012
基金项目:国家自然科学基金(批准号:20577014).
摘    要:利用UV/O3法对糠醛废水中的乙酸进行光氧化降解实验. 讨论了pH值、 光源、 阴阳离子等因素对乙酸降解速率的影响. 结果表明, 以高压汞灯 (400 W)为光源, 对500 mL浓度为8 mmol/L的乙酸溶液, 在温度为(35±2) ℃、 O3含量为 0.1 mg/L, pH值为2.2的条件下, 乙酸降解效果最佳. 在此条件下, 300 min内溶液中乙酸和TOC降解率分别为86%和74%. 在所考察浓度范围内, 乙酸的降解符合零级动力学模式.

关 键 词:UV/O3  乙酸  糠醛废水  光降解  
文章编号:1671-5489(2008)01-0162-04
收稿时间:2007-06-15
修稿时间:2007年6月15日

Influencing Factors of Photodegradation of Acetic Acid by UV/O3 Processes
KANG Chun-li,TANG Xiao-jian,GUO Ping,GUO Jing,YU Hong-bing.Influencing Factors of Photodegradation of Acetic Acid by UV/O3 Processes[J].Journal of Jilin University: Sci Ed,2008,46(1):162-165.
Authors:KANG Chun-li  TANG Xiao-jian  GUO Ping  GUO Jing  YU Hong-bing
Institution:College of Environment and Resources, Jilin University, Changchun 130012, China
Abstract:Acetic acid is the most important component of furfural wastewater, which was degraded by UV/O3 method. Effects of pH value, light intensity and negative and positive ions on the reaction were investigated. The results show the optimal conditions of the photodegradation reaction of 500 mL of 8 mmol/L acetic acid were pH=2.2, the temperature was (35±2) ℃ and the supply of O3 was 0.1 mg/L under 400 W ultraviolet radiation. Under those conditions, the disposal rates of acetic acid and TOC reached 86% and 74% within 300 min. The degradation course obeys the zero order kinetic equation.
Keywords:UV/O3  acetic acid  furfural wastewater  photodegradation
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