| 非重氮化法合成偶氮化合物1,2,3,4,5,6-三(4-偶氮苯基)苯 |
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| 引用本文： | 魏荣宝,郭金晶,李洪波,梁娅,孙伟.非重氮化法合成偶氮化合物1,2,3,4,5,6-三(4-偶氮苯基)苯[J].天津理工大学学报,2007,23(6):1-2. |
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| 作者姓名： | 魏荣宝 郭金晶 李洪波 梁娅 孙伟 |
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| 作者单位： | 天津理工大学,化学化工学院,天津,300191 |
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| 基金项目： | 国家自然科学基金;天津市自然科学基金 |
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| 摘 要： | 本实验通过基础原料苯肼和1,4-环己二酮合成了1,4-环己二酮单苯腙(1),(1)在乙醇和二氯亚砜作用下三聚芳构化得到了1,2,3,4,5,6-三(4-偶氮苯基)苯(2),从而通过重氮化法合成了一种新型的偶氮化合物.该法操作简单,对环境友好,为生产偶氮化合物提供了新的途径.
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| 关 键 词： | 偶氮化合 1 4-环己二酮 苯肼 芳构化 非重氮化法 1 2 3 4 5 6-三(4-偶氮苯基)苯 |
| 文章编号： | 1673-095X（2007）06-0001-02 |
| 收稿时间： | 2007-05-17 |
| 修稿时间： | 2007年5月17日 |
Synthesis of 2,6,10-tris(phenylazo)-1,2,3,4,5,6,7,8,9,10,11,12-dodecahydrotriphenylene by a non-diazotization method |
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| WEI Rong-bao,GUO Jin-jing,LI Hong-bo,LIANG Ya,SUN Wei.Synthesis of 2,6,10-tris(phenylazo)-1,2,3,4,5,6,7,8,9,10,11,12-dodecahydrotriphenylene by a non-diazotization method[J].Journal of Tianjin University of Technology,2007,23(6):1-2. |
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| Authors: | WEI Rong-bao GUO Jin-jing LI Hong-bo LIANG Ya SUN Wei |
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| Abstract: | 4-(phenyl-hydrazono)-cyclohexanone(1) was synthesized from phenylhydrazine and 1,4-cyclohexanedione.2,6,10-tris(phenylazo)-1,2,3,4,5,6,7,8,9,10,11,12-dodecahydrotriphenylene(2) was prepared by trimerization and aromatization of 1 in the presence of thionyl chloride in anhydrous ethanol.The new type of azostuff(2) was produced by a non-diazotiation method which was simple and safe to the environment.It provided a new method for the synthesis of azo-compounds. |
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| Keywords: | azo-compound 1 4-cyclohexandione phenylhydrazine aromatization non-diazotiation method 2 6 10-tris(phenylazo)-1 2 3 4 5 6 7 8 9 10 11 12-dodecahydrotriphenylene |
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