| 表面增强拉曼光谱研究尼古丁与金属纳米粒子的相互作用 |
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| 引用本文： | 刘自纯,李文嘉,余洁,李为娇,胡兰兰,金姗霞,李跃英,叶勇.表面增强拉曼光谱研究尼古丁与金属纳米粒子的相互作用[J].湖北大学学报(自然科学版),2011,33(4):521-524,532. |
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| 作者姓名： | 刘自纯 李文嘉 余洁 李为娇 胡兰兰 金姗霞 李跃英 叶勇 |
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| 作者单位： | 湖北大学化学化工学院,湖北武汉,430062 |
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| 摘 要： | 以金、银纳米及Au@Ag、Au-Ag合金复合纳米粒子为基底,研究尼古丁分子的表面增强拉曼光谱,讨论分子在4种纳米粒子表面的作用方式及可能的吸附取向.结果表明,分子在金纳米和Au-Ag合金纳米粒子表面的吸附取向相同——垂直吸附,不同的是与金纳米粒子形成了稳定的N-Au键；由于银纳米粒子和Au@Ag核壳纳米粒子表面均富含大...
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| 关 键 词： | 表面增强拉曼光谱 尼古丁 金属纳米粒子 |
Surface-enhanced Raman spectral studies on the interaction between nicotine and metal nanoparticles |
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| LIU Zichun
,
LI Wenjia
,
YU Jie
,
LI Weijiao
,
HU Lanlan
,
JIN Shanxia
,
LI Yueying
,
YE Yong.Surface-enhanced Raman spectral studies on the interaction between nicotine and metal nanoparticles[J].Journal of Hubei University(Natural Science Edition),2011,33(4):521-524,532. |
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| Authors: | LIU Zichun LI Wenjia YU Jie LI Weijiao HU Lanlan JIN Shanxia LI Yueying YE Yong |
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| Institution: | (Scool of Chemistry and Chemical Engineering,Hubei University,Wuhan 430062,China) |
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| Abstract: | In present work,four adsorbing substrates（gold nanoparticles,silver nanoparticles,gold-silver core-shell nanoparticles and gold-silver alloy nanoparticles） were synthesized.The possible adsorption orientation and interaction behavior of nicotine on these adsorbing substrates were investigated respectively by the surface-enhanced Raman spectroscopy.It was concluded that the molecule was adsorbed on the surfaces of the gold and the gold-silver alloy nanoparticles,with a similar vertical adsorption orientation.Nicotine molecule interacted with the gold surface directly through the N—Au bond.However,as the surfaces of the silver and gold-silver core-shell were rich in Ag,the molecule employed an extremity adsorption orientation.Nicotine molecule interacted with the silver surface directly through the Ag—N bond and Ag—C bond. |
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| Keywords: | surface-enhanced Raman spectra nicotine metal nanoparticles |
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