Electronic Absorption Spectra of Copper ( Ⅱ) Sulphophthalocyanine and Aggregation of the Dye in Aqueous Solution |
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作者姓名: | 温演庆 姚永毅 朱谱新 吴大诚 吴玉蓉 |
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作者单位: | WEN Yan-qing(Textile Institute, Sichuan University, Chengdu 610065, China;Sichuan Inspection and Quarantine Bureau, Chengdu 610041, China) ;YAO Yong-yi(Textile Institute, Sichuan University, Chengdu 610065, China) ;ZHU Pu-xin(Textile Institute, Sichuan University, Chengdu 610065, China) ;WU Da-cheng(Textile Institute, Sichuan University, Chengdu 610065, China) ;WU Yu-rong(Chemistry College, Sichuan University, Chengdu 610065, China) ; |
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基金项目: | National Natural Science Foundation of China (No. 50673062) |
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摘 要: | ![]() Aggregation behavior of C.I. Direct Blue 86 was discussed using analyses of its UV-Vis spectra. The experiment results show that the dye molecules are inclined to aggregate in aqueous solution. Even in a very dilute solution of 0.050 μol/L, A618/A659 = 1. 239 8, showing that the dye monomers still coexist with its dimers. The strong aggregation trend may cause dye precipitates at a higher concentration, which is an important factor that should be considered in producing a formula of ink-jet inks containing the dye as a colorant.
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关 键 词: | 铜酞菁染料 电子吸收光谱学 染色 水溶液 |
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