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Electronic Absorption Spectra of Copper ( Ⅱ) Sulphophthalocyanine and Aggregation of the Dye in Aqueous Solution
作者姓名:温演庆  姚永毅  朱谱新  吴大诚  吴玉蓉
作者单位:WEN Yan-qing(Textile Institute, Sichuan University, Chengdu 610065, China;Sichuan Inspection and Quarantine Bureau, Chengdu 610041, China) ;YAO Yong-yi(Textile Institute, Sichuan University, Chengdu 610065, China) ;ZHU Pu-xin(Textile Institute, Sichuan University, Chengdu 610065, China) ;WU Da-cheng(Textile Institute, Sichuan University, Chengdu 610065, China) ;WU Yu-rong(Chemistry College, Sichuan University, Chengdu 610065, China) ;
基金项目:National Natural Science Foundation of China (No. 50673062)
摘    要:
Aggregation behavior of C.I. Direct Blue 86 was discussed using analyses of its UV-Vis spectra. The experiment results show that the dye molecules are inclined to aggregate in aqueous solution. Even in a very dilute solution of 0.050 μol/L, A618/A659 = 1. 239 8, showing that the dye monomers still coexist with its dimers. The strong aggregation trend may cause dye precipitates at a higher concentration, which is an important factor that should be considered in producing a formula of ink-jet inks containing the dye as a colorant.

关 键 词:铜酞菁染料  电子吸收光谱学  染色  水溶液
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