| 二茂铁基偶氮苯甲酸溶液的光化学和电化学行为 |
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| 引用本文： | 任碧野,张一,李崇清,刘新星,童真.二茂铁基偶氮苯甲酸溶液的光化学和电化学行为[J].华南理工大学学报(自然科学版),2010,38(8). |
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| 作者姓名： | 任碧野 张一 李崇清 刘新星 童真 |
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| 作者单位： | 华南理工大学,材料科学研究所,广东,广州,510640 |
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| 基金项目： | 国家自然科学基金资助项目 |
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| 摘 要： | 合成了一种新型的具有光活性和氧化还原活性的两亲性分子——4-(11-二茂铁基正十一烷氧基)偶氮苯甲酸(FcAzCOOH),采用元素分析、核磁共振氢谱和傅里叶变换红外光谱对产物进行了确认与表征.紫外-可见吸收光谱研究表明,FcAzCOOH在四氢呋喃溶液中具有很好的光致异构行为.循环伏安行为研究表明,FcAzCOOH在N,N-二甲基甲酰胺溶液中的电极过程为受扩散控制的可逆过程,紫外光照对FcAzCOOH的电化学行为几乎没有影响.
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| 关 键 词： | 偶氮苯 二茂铁 光化学 电化学 |
Photochemical and Electrochemical Behaviors of Ferroceneylazobenzoic Acid Solution |
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| Ren Bi-ye,Zhang Yi,Li Chong-qing,Liu Xin-xing,Tong Zhen.Photochemical and Electrochemical Behaviors of Ferroceneylazobenzoic Acid Solution[J].Journal of South China University of Technology(Natural Science Edition),2010,38(8). |
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| Authors: | Ren Bi-ye Zhang Yi Li Chong-qing Liu Xin-xing Tong Zhen |
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| Institution: | Ren Bi-ye Zhang Yi Li Chong-qing Liu Xin-xing Tong Zhen (Research Institute of Materials Science,South China University of Technology,Guangzhou 510640,Guangdong,China) |
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| Abstract: | A novel amphiphilic ferroceneylazobenzoic acid(FcAzCOOH) with optical and redox activities was synthesized,and the product was identified and characterized by means of elemental analysis,1H NMR and FT-IR.Then,the photochemical behavior of FcAzCOOH in tetrahydrofuran solution was invenstigated by means of UV-Vis,with an excellent photoisomerization behavior being discovered.Moreover,the electrochemical behavior of FcAzCOOH in polar DMF solution was analyzed by means of cyclic voltammetry.The results show tha... |
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| Keywords: | azobenzene ferrocene photochemistry electrochemistry |
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