| 导电聚合物PNQMAn-Al3+的荧光性质 |
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| 引用本文： | 时雨荃,徐丹,艾小康,胡明,朱勇.导电聚合物PNQMAn-Al3+的荧光性质[J].天津大学学报(自然科学与工程技术版),2006,39(1):25-28. |
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| 作者姓名： | 时雨荃 徐丹 艾小康 胡明 朱勇 |
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| 作者单位： | [1]天津大学理学院,天津300072 [2]中国海洋大学化学化工学院,青岛266003 [3]天津大学电子信息工程学院,天津300072 [4]天津大学化工学院,天津300072 |
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| 基金项目： | 中国科学院资助项目;天津市科委资助项目 |
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| 摘 要： | 为研究导电聚苯胺衍生物与金属离子在溶液中形成的配合物的荧光性质，采用化学氧化法合成了导电聚合物聚N-5-（8-羟基喹啉）甲基]苯胺（PNQMAn），对本征态和盐酸掺杂的聚N-5-（8-羟基喹啉）甲基]苯胺在溶液中与Al^3＋形成的配合物的二维和三维荧光光谱进行了表征．结果表明，PNQMAn无论掺杂与否，在溶液中与铝离子形成的配合物都具有较好的荧光性．
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| 关 键 词： | 导电聚合物 荧光特性 聚苯胺 铝(Ⅲ)配合物 |
| 文章编号： | 0493-2137（2006）01-0025-04 |
| 收稿时间： | 2004-08-24 |
| 修稿时间： | 2004-08-242004-10-19 |
Fluorescence Property of Conducting Complex of PNQMAn-Al3+ |
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| SHI Yu-quan,XU Dan,AI Xiao-kang,HU Ming,ZHU Yong.Fluorescence Property of Conducting Complex of PNQMAn-Al3+[J].Journal of Tianjin University(Science and Technology),2006,39(1):25-28. |
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| Authors: | SHI Yu-quan XU Dan AI Xiao-kang HU Ming ZHU Yong |
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| Institution: | 1. School of Sciences, Tianjin University, Tianjin 300072, China; 2. School of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266003, China; 3. School of Electronic Information Engineering, Tianjin University, Tianjin 300072, China; 4. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China |
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| Abstract: | To study the fluorescence properties of the conducting polyaniline (PAn) derivatives and the corresponding complexes in solution with metal ion,a novel conducting polymer of poly N-5-(8-quinolinol) yl-methyl] -aniline ( PNQMAn) was synthesized by chemical oxidation. 2- and 3-dimension fluorescent spectrum of the complex of intrinsic and doped PNQMAn coordinated with Al3 in solution were studied. The result shows that, whether doped or not, the complex of PNQMAn coordinated with Al3 in solution has better fluorescence. |
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