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Cobalt doped titanate nanotubes: Synthesis and properties
Authors:Kai Zhang  Lin Lin  Li Li  Siwei Pan  Peiqi Wu  Xiaofeng Li  Aoshun Liu  Haining Zhang
Affiliation:1.Electric Power Research Institute of Guangdong Power Grid Company Ltd.,Guangdong,China;2.The 6th Affiliated Hospital of Sun Yat-sen University,Guangdong,China;3.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Hubei,China
Abstract:Cobalt oxide doped titanate nanotubes are synthesized with a simple hydrothermal treatment of mixed Co3O4 and TiO2 powders. The formed tubular nanostructure, chemical composition, and the elemental distribution are analyzed using TEM, BET, FTIR, XRD, and XPS. The electrocatalytic activity towards oxygen evolution reactions and photodegradation against Rhodamine B are investigated. It has been found out that the oxygen evolutions starts at 0.8 V and reaches 0.98 mA·cm–1 at 1.4 V vs. SCE. For photodegradation of Rhodamine B, the concentration decreased to 24% after 1 h irradiation using the sample with a mass percentage of 5% cobalt. The results demonstrate that the cobalt oxide doped titanate nanotubes are good candidates as electrocatalysts and photocatalytic materials.
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