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邻硝基苯酚在黄河沉积物和水相间的平衡分配
引用本文:李改枝,刘颖,李景峰,郭博书.邻硝基苯酚在黄河沉积物和水相间的平衡分配[J].宁夏大学学报(自然科学版),2001,22(4):437-439.
作者姓名:李改枝  刘颖  李景峰  郭博书
作者单位:内蒙古师范大学化学系,内蒙古,呼和浩特,010022
基金项目:内蒙古自治区自然科学基金资助项目 (2 0 0 0 130 1)
摘    要:研究了邻硝基苯酚在黄河沉积物和水相间的分配行为,计算出中性分子和离子形态的分配系数Kd,Kdi以及总分配系数Kdo,结果表明,分配行为与体系的pH值有关,中性分子的分配系数Kd随pH增大而增大,中性分子和离子形态的总分配系数Kdo在pH大于6.12时减小,当pH大于5.08时,吸附态分数在0.85以上。

关 键 词:邻硝基苯酚  黄河  沉积物    平衡分配  污染物
文章编号:0253-2328(2001)04-0437-03
修稿时间:2001年3月5日

Equilibrium partition behavior of o-nitrophenol between sediments and aqueous phase in the Yellow River
LI Gai-zhi,LIU Ying,LI Jing-feng,GUO Bo-shu.Equilibrium partition behavior of o-nitrophenol between sediments and aqueous phase in the Yellow River[J].Journal of Ningxia University(Natural Science Edition),2001,22(4):437-439.
Authors:LI Gai-zhi  LIU Ying  LI Jing-feng  GUO Bo-shu
Abstract:The equilibrium partition coefficients K d, K di and total partition coefficient K do of neutral molecule and charged ion of o-nitrophenol were calculated in the samples taken from the Yellow River. The results show that partitioning behavior relates with pH of the system. The partition coefficient K d of neutral molecule increases with system's pH increasing. The total partition coefficient K do of neutral molecule and charged ion decreases when system's pH is higher than 6.12, and the part of adsorption is more than 0.85 when system's pH is above 5.08.
Keywords:o-nitrophenol  partition coefficient  sediment  the Yellow River
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