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氧化石墨烯-壳聚糖复合材料对甲烯蓝的吸附动力学
引用本文:徐静,闻宏亮,欧阳建波,王宁,杨胜韬.氧化石墨烯-壳聚糖复合材料对甲烯蓝的吸附动力学[J].上海大学学报(自然科学版),2013,19(4):400-404.
作者姓名:徐静  闻宏亮  欧阳建波  王宁  杨胜韬
作者单位:(西南民族大学化学与环境保护工程学院, 成都610041)
基金项目:西南民族大学中央高校基本科研业务费专项资金资助项目(13NZYQN14)
摘    要:氧化石墨烯-壳聚糖复合材料(graphene oxide-chitosan composite, GO-CS) 可用于清除阳离子染料, 具有吸附量大、易于分离等优点. 对GO-CS吸附阳离子染料甲烯蓝的动力学进行了研究, 结果显示, GO-CS对甲烯蓝的吸附符合二级动力学模型. 颗粒内扩散模型分析表明, GO-CS 吸附甲烯蓝的扩散机制包括颗粒内扩散和表面扩散.此外, 还发现GO-CS 对甲烯蓝的吸附量受pH 值和离子强度的影响, 较高的pH 值和离子强度有利于提高吸附量.

关 键 词:甲烯蓝  吸附动力学  氧化石墨烯-壳聚糖  印染废水  

Adsorption Kinetics of Methylene Blue on Graphene Oxide-Chitosan Composite
XU Jing;WEN Hong-liang;OUYANG Jian-bo;WANG Ning;YANG Sheng-tao.Adsorption Kinetics of Methylene Blue on Graphene Oxide-Chitosan Composite[J].Journal of Shanghai University(Natural Science),2013,19(4):400-404.
Authors:XU Jing;WEN Hong-liang;OUYANG Jian-bo;WANG Ning;YANG Sheng-tao
Institution:(College of Chemistry and Environment Protection Engineering, Southwest University for Nationalities,; Chengdu 610041, China)
Abstract:Graphene oxide-chitosan composite (GO-CS) is powerful in decoloration of cationic dyes. GO-CS holds several advantages including high adsorption capacity and easy separation after adsorption. This paper investigates the adsorption kinetics of methylene blue on GO-CS. The adsorption process is nicely described by a pseudo-second-order model. The diffusion mechanism includes intraparticle diffusion and surface diffusion.The adsorption capacity of GO-CS can be regulated by pH and ionic strength, where higher pH and ionic strength were preferred.
Keywords:adsorption kinetics  dyeing wastewater  graphene oxide-chitosan  methylene blue  
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