| MNT和DNT同分异构体的偶极矩实测和计算 |
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| 引用本文： | 江明,丁海清,俞马宏,朱堂烈,肖鹤鸣,高怀琳.MNT和DNT同分异构体的偶极矩实测和计算[J].南京理工大学学报(自然科学版),1992(2). |
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| 作者姓名： | 江明 丁海清 俞马宏 朱堂烈 肖鹤鸣 高怀琳 |
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| 作者单位： | 华东工学院化工学院
(江明,丁海清,俞马宏,朱堂烈,肖鹤鸣),北京理工大学化学工程系(高怀琳) |
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| 摘 要： | 用“溶液法”实测了o-、m-、p-MNT和2,3-、2,4-、2,5-、2,6-、3,4-以及3,5-DNT共9个化合物在CCl_4溶液中的偶极矩;用MINDO/3法计算了它们的气相偶极矩。二者符合良好,线性相关系数为0.996。
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| 关 键 词： | 偶极矩 硝基甲苯 二硝基甲苯 MINDO/3计算 |
Observation and Calculation of Dipole Moments of MNT and DNT Isomerides. |
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| Jiang Ming School of Chemical Engineering.Observation and Calculation of Dipole Moments of MNT and DNT Isomerides.[J].Journal of Nanjing University of Science and Technology(Nature Science),1992(2). |
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| Authors: | Jiang Ming School of Chemical Engineering |
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| Institution: | Jiang Ming School of Chemical Engineering |
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| Abstract: | The dipole moments of nine compounds (o-, m-, p-MNT and2, 3-, 2, 4-, 2 , 5-, 2, 6-, 3, 4-, 3 , 5-DNT) in CCl_4 solution have been observedby using"solution method",and calculated in gas phase by using MINDO/3method. The experimental and calculated results comform to each other andthe linear correlation coefficient is 0. 996. |
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| Keywords: | dipole moment nitrotoluene dinitrotoluene MINDO/3 calculation |
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