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石墨烯/二氧化锰复合材料的制备及其电化学性能
引用本文:周龙斐,邱红梅,徐美,路彦珍,胡建玲,王子娅,王凤平.石墨烯/二氧化锰复合材料的制备及其电化学性能[J].北京科技大学学报,2016(9):1300-1305.
作者姓名:周龙斐  邱红梅  徐美  路彦珍  胡建玲  王子娅  王凤平
作者单位:北京科技大学数理学院,北京,100083
基金项目:中央高校基础科研基金资助项目(FRF-AS-13-004A;FRF-BR-14-024A),北京科技大学基本科研业务费资助项目(FRF-BR-14-024A),北京高等学校青年英才计划资助项目(YETP0390)
摘    要:通过水热法在160℃条件下成功制备了手风琴状石墨烯/MnO2复合材料.通过场发射扫描电镜、透射电镜、X射线衍射、X射线能量色散谱、BET法以及拉曼光谱对材料进行表征.结果表明,手风琴状二氧化锰与层状石墨烯之间具有十分高效的贴合,这种创新性设计有效地利用了石墨烯的高电导率、大比表面积以及二氧化锰的优秀赝电容行为.电化学测试结果给出在0.2 A·g-1时,样品的比电容高达138 F·g-1,数倍增强于单独的二氧化锰或石墨烯样品.

关 键 词:二氧化锰  石墨烯  水热合成  超级电容器

Synthesis and electrochemical properties of graphene/MnO2 composites
ZHOU Long-fei,QIU Hong-mei,XU Mei,LU Yan-zhen,HU Jian-ling,WANG Zi-ya,WANG Feng-ping.Synthesis and electrochemical properties of graphene/MnO2 composites[J].Journal of University of Science and Technology Beijing,2016(9):1300-1305.
Authors:ZHOU Long-fei  QIU Hong-mei  XU Mei  LU Yan-zhen  HU Jian-ling  WANG Zi-ya  WANG Feng-ping
Abstract:Accordion-like MnO2-coated graphene composites were successfully prepared by a facile hydrothermal method at 160℃. The as-products were characterized by field emission scanning electron microscopy, transmission electron microscopy, X-ray dif-fraction, energy dispersive spectrometry, BET and Raman spectroscopy. The high capacitance of 138 F·g-1 at 0. 2 A·g-1 is achieved with MnO2/graphene composites as a supercapacitor electrode, much higher than that of a single MnO2 or graphene electrode. The ex-cellent electrochemical performance is attributed to the uniform MnO2 nanosheet morphology, large surface area of graphene and stable chemical bonding of MnO2 on the graphene substrate.
Keywords:manganese dioxide  graphene  hydrothermal synthesis  supercapacitors
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