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电镀锌钢板CrO3—H3PO4—SiO2体系钝化膜
引用本文:卢燕平,任玉苓.电镀锌钢板CrO3—H3PO4—SiO2体系钝化膜[J].北京科技大学学报,1997,19(4):355-359.
作者姓名:卢燕平  任玉苓
作者单位:北京科技大学材料科学与工程学院!北京,100083(卢燕平,吴继勋),宝山钢铁(集团)公司!上海,201900(任玉苓)
摘    要:研究了电镀锌钢板CrO3-H3PO4-SiO2体系钝化膜的成分与结构,并对钝化膜的耐蚀性及其原因进行了探讨,结果表明,该钝化膜是1种由CrO3,Cr(OH)3,CrOOH,ZnCrO4,ZnSiO3,Zn3(PO4)2,CrPO4和SiO2等化合物组成的,具有凝胶网络状结构的厚型复合转化膜,这种膜具有良好的屏蔽效应和缓蚀作用,能明显了改善镀锌钢板抗白锈的能力,它的耐蚀性是CrO3-SiO2体系钝化

关 键 词:铬酸盐  腐蚀  纯化膜  钢板  镀锌  电镀

Passive Film Formed from CrO_3-H_3PO_4-SiO_2 Systems on Galvanized Steel Sheet
Lu Yanping, Ren Yuling, Wu Jixun.Passive Film Formed from CrO_3-H_3PO_4-SiO_2 Systems on Galvanized Steel Sheet[J].Journal of University of Science and Technology Beijing,1997,19(4):355-359.
Authors:Lu Yanping  Ren Yuling  Wu Jixun
Abstract:The composition and structure of passive film formed from CrO3-H3PO4SiO2, systems on galvanized steel sheet were inveshgated, the corrosion resistance and itsprotective causes of the film were also discussed. The experimental results showed thatthe film is a thick type of complex conversion coating with gelatinous net structurecontaining Cro3, Cr(OH)3, CrOOH, ZnCrO4, ZnSiO3,, Zn3(PO3)2, CrPO4 and SiO2, etC. Thewhite rust-resisting property of the film is of three times better than that of filmformed from CrO3, - SiO2, systems because of good shielding and inhibihng.
Keywords:galvanized steel sheet  chromate  conversion coating  corrosion
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