| 缩聚磷酸苯酯缩合反应动力学研究 |
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| 引用本文： | 吴燕翔,王良恩,朱跃姿.缩聚磷酸苯酯缩合反应动力学研究[J].福州大学学报(自然科学版),1994(2):93-97. |
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| 作者姓名： | 吴燕翔 王良恩 朱跃姿 |
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| 作者单位： | 福州大学化学工程系 |
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| 摘 要： | 对ＰＯＣｌ３与对苯二酚缩合反应动力学进行了研究，对反应机理作了推测，提出了反应本征动力学方程。宏观动力学测定表明反应拟为一级，其表观活化能为８６．２ｋＪ／ｍｏｌ．
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| 关 键 词： | 缩聚磷酸酯 机理 动力学 |
Kinetics of Condensation Reaction in Preparation of Polyaromatic Phosphate |
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| Wu yanxiang,Wang Liangen,Zhu Yuezhi.Kinetics of Condensation Reaction in Preparation of Polyaromatic Phosphate[J].Journal of Fuzhou University(Natural Science Edition),1994(2):93-97. |
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| Authors: | Wu yanxiang Wang Liangen Zhu Yuezhi |
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| Institution: | Wu yanxiang;Wang Liangen;Zhu Yuezhi(Department of Chemical Engineering,Fuzhou University, Fuzhou, 350002) |
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| Abstract: | in this paper, the kinetics of condensation reaction of POCl_3 and hydroquinone is studied. The intrinsic kinetic equation is obtained. The experimental data show that the reaction is of first grade,with the apparent activation energy of 86.2 KJ/mol. |
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| Keywords: | polyarmatic phosphate kinetics mechanism |
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