| 1,3,5-三(4-(烯丙氧基)苯基)-1,3,5-三嗪的合成 |
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| 引用本文： | 张爱清,区文彩.1,3,5-三(4-(烯丙氧基)苯基)-1,3,5-三嗪的合成[J].中南民族大学学报(自然科学版),2010,29(1):10-13. |
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| 作者姓名： | 张爱清 区文彩 |
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| 作者单位： | 中南民族大学,化学与材料科学学院催化材料科学湖北省暨国家民委-教育部共建重点实验室,武汉,430074 |
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| 基金项目： | 国家中小企业创新基金 |
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| 摘 要： | 以对乙酰氨基酚、氯丙烯为原料合成了4-烯丙氧基乙酰苯胺,4-烯丙氧基乙酰苯胺经盐酸水解得到4-烯丙氧基苯胺,2步反应的总产率为66.5%.4-烯丙氧基苯胺与甲醛水溶液反应得到1,3,5-三(4-(烯丙氧基)苯基)-1,3,5-三嗪,产率为70.9%.采用傅里叶红外光谱(FT-IR)和核磁共振(1H-NM R)对目标产物及其中间体进行了表征.
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| 关 键 词： | 4-烯丙氧基苯胺 三嗪 苯并噁嗪 |
Synthesis of 1,3,5-Tri-(4-(Allyloxy)Phenyl)-1,3,5-Triazine |
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| Zhang Aiqing,Qu Wencai.Synthesis of 1,3,5-Tri-(4-(Allyloxy)Phenyl)-1,3,5-Triazine[J].Journal of South-Central Univ for,2010,29(1):10-13. |
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| Authors: | Zhang Aiqing Qu Wencai |
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| Institution: | Zhang Aiqing,Ou Wencai (Key Laboratory of Catalysis , Materials Science of the State Ethnic Affair Commission &Ministry of Education,Hubei Provinc,South-Central University for Nationalities,Wuhan 430074,China) |
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| Abstract: | N-4-(allyloxy)phenyl]acetamide was prepared by the reaction of paracetamol with 3-chloropropylene,and 4-(allyloxy)aniline was produced from N-4-(allyloxy)phenyl]acetamide by acid hydrolysis,the total yield of two-step reaction is 66.5%.Then 1,3,5-tri-(4-(allyloxy)phenyl)-1,3,5-triazine was synthesized from 4-(allyloxy)aniline and aqueous solution of formaldehyde in 70.9 % yield.These compounds have been characterized by FT-IR and 1H-NMR. |
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| Keywords: | 4-(allyloxy)aniline triazine benzoxazine |
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