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微波辐射合成聚丙烯酸-海藻酸钠高吸水树脂
引用本文:沈莉,王珊珊,牛少莉,方明.微波辐射合成聚丙烯酸-海藻酸钠高吸水树脂[J].河北科技师范学院学报,2014(2):37-41.
作者姓名:沈莉  王珊珊  牛少莉  方明
作者单位:河北科技师范学院化学工程学院,河北秦皇岛066600
基金项目:秦皇岛市科学技术研究与发展项目(项目编号:201302A039)
摘    要:以海藻酸钠和丙烯酸为原料,采用微波辐射法接枝共聚制备了聚丙烯酸(AA)-海藻酸钠(SA)高吸水树脂。探讨了交联剂及引发剂的用量、单体配比、丙烯酸中和度、微波功率等因素对树脂吸水倍率的影响规律,并进行了树脂吸水速率和保水性能的研究,用红外光谱对树脂结构进行表征。实验结果表明,该树脂在蒸馏水中的吸水倍率为733.92 g/g,在生理盐水中的吸水倍率为120.68 g/g,并且具有较快的吸水速率及良好的保水性能。

关 键 词:微波辐射  海藻酸钠  高吸水树脂  吸水倍率

Synthesis of Super Absorbent Polymer of Alginate-acrylic by Microwave
SHEN Li,WANG Shan-shan,NIU Shao-li,FANG Ming.Synthesis of Super Absorbent Polymer of Alginate-acrylic by Microwave[J].Journal of Hebei Normal University of Science & Technology,2014(2):37-41.
Authors:SHEN Li  WANG Shan-shan  NIU Shao-li  FANG Ming
Institution:( College of Chemical Engineering, Hebei Normal University Science & Technolegy, Qinhuangdao Hebei ,066600 ,China)
Abstract:Using sodium alginate and acrylic acid as row material,Polyacrylic acid-alginate superabsorbent resin was synthesized with microwave polymerization.The impact of factors on water absorption of rensin,such as the amount of crosslinking agent and initiator,the ratio of monomers,neutralization degree of acrylic acid,the power and time of microwave and so on,were discussed.The results showed that water absorption was733.92 g/g in distelled water and 120.68 g/g in nomal saline.The resin has a high water-absorption rate and good water retention properties.
Keywords:sodium alginate  Super absorbent resin  microwave  water absorption
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