混合法合成二阶氯化铁-石墨层间化合物的研究

在前期合成纯一阶ＦｅＣｌ３－ＧＩＣ工作的基础上，设计了混合法合成二阶ＦｅＣｌ３－ＧＩＣ的实验方案，考察了反应温度、Ｃ和ＦｅＣｌ３摩尔比ｎ（Ｃ）／ｎ（ＦｅＣｌ３），保温时间对产物阶结构的影响。首次用混合法合成了纯二阶Ｆｅ－Ｃｌ３－ＧＩＣ，确立了其最佳反应条件。

Study on the Synthesis of the Stage-2 FeCl_3-GIC Using the Mixing Method

Based upon our previous work on the synthesis of the pure stage 1 FeCl 3 GIC,the experimental program of the synthesis of the pure stage 2 FeCl 3 GIC was designed.The influences of the reaction temperature,the ratio of C/FeCl 3 and the soaked time on the stage structure of the resultant were investigated.And the pure stage 2 FeCl 3 GIC was synthesized using the mixing method firstly while the optimum reaction condition was determined.