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聚苯乙烯磺酸钠对水泥净浆性能的影响
引用本文:罗青枝,王德松,朱学旺,李发堂,安静,马旭辉. 聚苯乙烯磺酸钠对水泥净浆性能的影响[J]. 河北科技大学学报, 2005, 26(2): 114-117
作者姓名:罗青枝  王德松  朱学旺  李发堂  安静  马旭辉
作者单位:河北科技大学理学院,河北,石家庄,050018;河北科技大学理学院,河北,石家庄,050018;河北科技大学理学院,河北,石家庄,050018;河北科技大学理学院,河北,石家庄,050018;河北科技大学理学院,河北,石家庄,050018;河北科技大学理学院,河北,石家庄,050018
基金项目:河北省博士基金资助项目(00547001D1),河北省教育厅科研基金资助项目(2001227)
摘    要:以废弃的聚苯乙烯为原料制备聚苯乙烯磺酸钠(SPS),考察了SPS对水泥净浆性能的影响。结果表明:向水泥基体中加入微量(例如水泥质量的10-5%)的SPS,水泥净浆的吸水率和化学结合水量减小,抗压强度、抗折强度和冲击强度增大;随着SPS掺量的增大,水泥净浆的吸水率和化学结合水量进一步减小,抗压强度、抗折强度和冲击强度进一步提高;但SPS掺量超过水泥质量的10-3%后,水泥净浆的吸水率略有增大,抗压强度、抗折强度和冲击强度略有降低;SPS的相对分子质量和磺化度对水泥净浆的性能几乎没有影响。

关 键 词:聚苯乙烯  磺化反应  水泥  水泥净浆  理化性能
文章编号:1008-1542(2005)02-0114-04
修稿时间:2004-12-01

Effect of poly(sodium styrenesulfonate) on cement paste properties
LUO Qing-zhi,WANG De-song,ZHU Xue-wang,LI Fa-tang,AN Jing and MA Xu-hui. Effect of poly(sodium styrenesulfonate) on cement paste properties[J]. Journal of Hebei University of Science and Technology, 2005, 26(2): 114-117
Authors:LUO Qing-zhi  WANG De-song  ZHU Xue-wang  LI Fa-tang  AN Jing  MA Xu-hui
Affiliation:College of Sciences,Hebei University of Science and Technology,Shijiazhuang Hebei 050018, China;College of Sciences,Hebei University of Science and Technology,Shijiazhuang Hebei 050018, China;College of Sciences,Hebei University of Science and Technology,Shijiazhuang Hebei 050018, China;College of Sciences,Hebei University of Science and Technology,Shijiazhuang Hebei 050018, China;College of Sciences,Hebei University of Science and Technology,Shijiazhuang Hebei 050018, China;College of Sciences,Hebei University of Science and Technology,Shijiazhuang Hebei 050018, China
Abstract:Poly(sodium styrenesulfonate)(SPS) is prepared from the waste polystyrene by sulfonation with sulfuric acid as sulfonation agent. The effect of SPS on the cement paste properties has been studied. The result shows that the addition of SPS into cement pastes can decrease their water absorption and chemically combine water content, and increase their compressive strength, bending strength and impact strength. The water absorption and chemically combined water content continually decrease, and the compressive strength, bending strength and impact strength continually increase as SPS content increases. But the water absorption slightly increase and the compressive strength, bending strength and impact strength slightly decrease when the SPS contents exceed 10 -3% of the cement mass. The molecular weight and sulfonation degree of SPS have little effect on the cement paste properties.
Keywords:polystyrene  sulfonation  cement  cement paste  property
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