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Lead-bismuth-free piezoceramics (Na0.5K0.44Li0.06)Nb0.95Sb0.05O3-Na5.6Cu1.2Sb10O29
作者姓名:ZHENG  LiMei  WANG  JinFeng  ZANG  GuoZhong  ZHAO  MingLei  QI  Peng  DU  Juan  SU  WenBin  MING  BaoQuan
作者单位:School of Physics and Microelectronics, State Key Laboratory of Crystal Materials, Shandong University, Ji'nan 250100, China
基金项目:Supported by the National Natural Science Foundation of China (Grant No. 50572056), the Natural Science Foundation of Shandong Province, China (No. Z2003F04) and the Basic Science Talent Training Foundation of China
摘    要:Newly developed sintering aid Na5.6Cu1.2Sb10O29 (NCS) and lead-bismuth-free piezoceramics (Na0.5K0.44Li0.06) Nb0.95Sb0.05O3 (NKLNS) were prepared by the conventional solid state reaction. The effects of sintering aid NCS on the electrical properties of NKLNS were investigated. It was found that the addition of a proper amount of sintering aid NCS to NKLNS is effective not only on improving the density and the piezoelectric activity, but also on reducing the dielectric loss of NKLNS. The NKLNS doped with 0.4 mol% NCS has a piezoelectric constant d33 as high as 261pC/N and an electromechanical coupling factor k33 above 60%. These results show that NCS-doped NKLNS is a promising and practicable candidate for lead-bismuth-free piezoceramics.

关 键 词:无铅无铋压电陶瓷  相变  铌酸盐  钽酸盐
收稿时间:29 March 2006
修稿时间:2006-03-292006-05-09

Lead-bismuth-free piezoceramics (Na0.5K0.44Li0.06)Nb0.95Sb0.05O3-Na5.6Cu1.2Sb10O29
ZHENG LiMei WANG JinFeng ZANG GuoZhong ZHAO MingLei QI Peng DU Juan SU WenBin MING BaoQuan.Lead-bismuth-free piezoceramics (Na0.5K0.44Li0.06)Nb0.95Sb0.05O3-Na5.6Cu1.2Sb10O29[J].Chinese Science Bulletin,2007,52(4):566-569.
Authors:ZHENG LiMei  WANG JinFeng  ZANG GuoZhong  ZHAO MingLei  QI Peng  DU Juan  SU WenBin  MING BaoQuan
Institution:(1) School of Physics and Microelectronics, State Key Laboratory of Crystal Materials, Shandong University, Ji’nan, 250100, China
Abstract:Newly developed sintering aid Na5.6Cu1.2Sb10O29 (NCS) and lead-bismuth-free piezoceramics (Na0.5K0.44Li0.06) Nb0.95Sb0.05O3 (NKLNS) were prepared by the conventional solid state reaction. The effects of sintering aid NCS on the electrical properties of NKLNS were investigated. It was found that the addition of a proper amount of sintering aid NCS to NKLNS is effective not only on improving the density and the piezoelectric activity, but also on reducing the dielectric loss of NKLNS. The NKLNS doped with 0.4 mol% NCS has a piezoelectric constant d33 as high as 261pC/N and an electromechanical coupling factor k33 above 60%. These results show that NCS-doped NKLNS is a promising and practicable candidate for lead-bismuth-free piezoceramics.
Keywords:lead-bismuth-free piezoceramics  niobate  tantalate  electromechanical coupling factor  phase transition
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