| 树枝酞菁锌-单壁碳纳米管复合体系的合成 |
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| 引用本文： | 吴克勤,刘静,马冬冬,贸丹丹,陈婉玲,林秋云,邱燕珠,彭亦如.树枝酞菁锌-单壁碳纳米管复合体系的合成[J].厦门大学学报(自然科学版),2011,50(Z1):70-73. |
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| 作者姓名： | 吴克勤 刘静 马冬冬 贸丹丹 陈婉玲 林秋云 邱燕珠 彭亦如 |
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| 作者单位： | 福建师范大学化学与材料学院,福建 福州,350007 |
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| 基金项目： | 国家自然科学基金，福建省科技厅重点项目，福建省自然科学基金，卫生部科学研究基金，福建省大学生创新性实验计划项目 |
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| 摘 要： | 利用乙二胺对单壁碳纳米管进行氨基化修饰,进一步与四-3,5-(二-4-羧基苯甲氧基)-苯甲氧基]锌酞菁发生酰基化反应.树枝酞菁锌-单壁碳纳米管化合物相对纯单壁碳纳米管能更好的溶解于有机溶剂二甲基甲酰胺中.通过紫外-可见吸收光谱和热重分析对所合成的树枝酞菁锌-单壁碳纳米管化合物进行了表征.本研究为碳纳米管在生物医学中的应用提供实验理论依据.
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| 关 键 词： | 树枝酞菁 单壁碳纳米管 紫外-可见吸收光谱 热重分析 |
Synthesis of Functionalized Single-walled Carbon Nanotubes with Dendritic Phthalocyanines |
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| WU Ke-qin,LIU Jing,MA Dong-dong,HE Dan-dan,CHEN Wan-ling,LIN Qiu-yun,QIU Yan-zhu,PENG Yi-ru.Synthesis of Functionalized Single-walled Carbon Nanotubes with Dendritic Phthalocyanines[J].Journal of Xiamen University(Natural Science),2011,50(Z1):70-73. |
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| Authors: | WU Ke-qin LIU Jing MA Dong-dong HE Dan-dan CHEN Wan-ling LIN Qiu-yun QIU Yan-zhu PENG Yi-ru |
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| Institution: | WU Ke-qin,LIU Jing,MA Dong-dong,HE Dan-dan,CHEN Wan-ling,LIN Qiu-yun,QIU Yan-zhu,PENG Yi-ru(College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,China) |
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| Abstract: | The motivation of this study was the fabrication of nanotube-based zinc-phthalocyanine(ZnPc),which may be a promising functional material.In this article,the functionalization of single-walled carbon nanotubes(SWNTs) was described with ethylenediamine and the subsequent attachment of the ZnPc derivative,tetra-(3,5-di(4-carboxyl benzyloxy)-benzyloxy) zinc phthalocyanine,using the reliable acylation reaction.The resulting SWNTs-ZnPc conjugate exhibits more excellent solubility in dimethyl formamide(DMF) than ... |
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| Keywords: | dendritic phthalocyanines single-walled carbon nanotubes ultraviolet-visible absorption spectroscopy thermogravimetric analysis |
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