| 金属苯的亲核加成和芳香亲核取代反应 |
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| 引用本文： | 林然,张弘,曹晓宇,夏海平.金属苯的亲核加成和芳香亲核取代反应[J].厦门大学学报(自然科学版),2011,50(Z1):1-4. |
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| 作者姓名： | 林然 张弘 曹晓宇 夏海平 |
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| 作者单位： | 厦门大学化学化工学院,福建 厦门,361005 |
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| 基金项目： | 教育部科技发展中心博士点基金，高等学校博士点新教师基金 |
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| 摘 要： | 近年来有关金属苯亲核反应的研究工作为证实金属苯的芳香性提供了有力的实验证据,发展了经典有机化学的芳香亲核取代反应理论.同时,借助金属苯亲核反应的研究还可获得一系列结构新颖的金属有机化合物.本文就迄今为止已报道的金属苯的亲核加成和芳香亲核取代反应进行了全面的总结.
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| 关 键 词： | 金属苯 芳香性 亲核加成反应 亲核取代反应 |
The Electrophilic Aromatic Addition and Substitution Reactions of Metallabenzenes |
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| LIN Ran,ZHANG Hong,CAO Xiao-yu,XIA Hai-ping.The Electrophilic Aromatic Addition and Substitution Reactions of Metallabenzenes[J].Journal of Xiamen University(Natural Science),2011,50(Z1):1-4. |
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| Authors: | LIN Ran ZHANG Hong CAO Xiao-yu XIA Hai-ping |
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| Institution: | LIN Ran,ZHANG Hong,CAO Xiao-yu,XIA Hai-ping(College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China) |
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| Abstract: | Significant progress of the nucleophilic aromatic substitution(SNAr) reaction of metallabenzenes has been made in recent years.SNAr reaction not only can provide strong chemical support for the aromaticity of the metallabenzene rings but also obtain new interesting organometallic complexes.All the SNAr reactions of metallabenzenes,which have been reported,are reviewed in this article. |
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| Keywords: | metallabenzene aromaticity nucleophilic aromatic addition reaction nucleophilic aromatic substitution reaction |
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