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鸡西煤化学结构的演化
引用本文:胡善亭,王淀佐,邱冠周.鸡西煤化学结构的演化[J].中南大学学报(自然科学版),1996(4).
作者姓名:胡善亭  王淀佐  邱冠周
作者单位:中南工业大学矿物工程系
基金项目:国家自然科学基金,第30届国际地质大会基金,中国博士后科学基金
摘    要:采用X射线衍射、红外光谱等手段对鸡西煤不同煤化作用阶段煤结构演化进行了研究.X射线衍射分析显示,随着煤化程度增加,反映芳香核大小的Lc和La都逐渐增加,而芳香层间距d002逐渐减小;红外光谱分析显示,不同变质程度煤中都含有芳烃,随着煤化程度加深,芳香核的缩合程度增加,醇、酚、羟基等侧链基团的吸收峰逐渐减弱.

关 键 词:X射线衍射  红外光谱  鸡西煤  煤结构  煤化程度

STUDY ON THE CHEMICAL STRUCTURE EVOLUTION OF JIXI COALS
Hu Shaming,Wang Dianzhuo, Qiu Guanzhou.STUDY ON THE CHEMICAL STRUCTURE EVOLUTION OF JIXI COALS[J].Journal of Central South University:Science and Technology,1996(4).
Authors:Hu Shaming  Wang Dianzhuo  Qiu Guanzhou
Abstract:The chemical structure evolution of coals in different coalification stages were studied using X-ray diffraction and infrared spectrometry. The result of X-ray diffraction analysis shows that with the increase of coalification the Lc and La that express the size of aromatic nucleus get bigger gradually, and the d002 that expresses the spacing of aromatic layers gets smaller. The result of infrared spectrometry expresses that the coals in any coalification all contain aromatic hydrocarbon, and with the increase of coalification the aromatic nucleus shrink more and the absorbing peaks of alcohol and phenolic hydroxyl group ect. weaken gradually.
Keywords:X-ray diffraction  infrared spectrometry  Jixi coal  coal structure  coalification stage
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