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天然丝光沸石在甲醇氨化反应中的催化作用
引用本文:毛丽秋 矫庆泽. 天然丝光沸石在甲醇氨化反应中的催化作用[J]. 湖南师范大学自然科学学报, 1998, 21(4): 51-54
作者姓名:毛丽秋 矫庆泽
作者单位:[1]湖南师范大学精细催化合成研究所 [2]吉林大学化学系
摘    要:
研究了吉林省东辽县天然丝光沸石催化甲醇氨化反应的规律,考察了酸处理,反应温度,反应物进料比和接触时间对样品催化性能的影响。通过XRD、NH3-TPD,Py(NH3)-IR等手段对催化剂的晶体结构和酸性进行了表征,得出了催化剂活性与其酸量存在对应关系的结论。

关 键 词:天然丝光沸石 甲胺 甲醇 氨化反应 催化作用

Study on the Catalytic Effect of Natural Mordenite Mineral on the Ammoniation of Methanol
Mao Liqiu Yin Dulin. Study on the Catalytic Effect of Natural Mordenite Mineral on the Ammoniation of Methanol[J]. Journal of Natural Science of Hunan Normal University, 1998, 21(4): 51-54
Authors:Mao Liqiu Yin Dulin
Abstract:
The present report concerns the law of the ammoniation of methanol catalyzed by natural mordenite mineral found in Dongliao country of Jinlin Province.The effect of acid treatment,reaction temperature,ratio of NH 3/CH 3OH and contact time on the catalytic performance has been investigated.The crystal struture and acidity of the samples were investigated by X ray diffraction,NH 3 temperature programmed desorption and pyridine (NH 3) infrared spectrometry etc.We have concluded that the catalytic activities of samples are in accord with their acid amount.
Keywords:natural mordenite  methylamine  Py IR
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