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碳分子筛分离氧氩过程的实验研究
引用本文:崔红社,刘应书,刘文海,乐恺,张德鑫. 碳分子筛分离氧氩过程的实验研究[J]. 北京科技大学学报, 2005, 27(4): 493-496
作者姓名:崔红社  刘应书  刘文海  乐恺  张德鑫
作者单位:1. 北京科技大学院机械工程学院,北京,100083;青岛建筑工程学院,青岛,266033
2. 北京科技大学院机械工程学院,北京,100083
摘    要:
基于碳分子筛动态吸附机理,建立了分离氧氩的实验装置.实验研究了流程形式、清洗比、吸附时间对碳分子筛分离氧氩过程性能的影响.结果表明,循环过程中增加产品气清洗阶段可以显著提高解吸气的纯度.为了得到质量分数为99.0%以上的氧气,循环过程中清洗比应控制在0.4左右,最佳吸附时间为60 s.以95%氧、5%氩的混合气作为原料气,实验装置的产品气纯度可以达到99.4%,氧气回收率为42%.

关 键 词:碳分子筛  氧氩分离  变压吸附  清洗比  高浓度氧  碳分子筛  分离  循环过程  实验装置  研究  molecular sieves  carbon  argon  oxygen  separation  study  回收率  产品气纯度  原料气  混合气  最佳  控制  氧气  质量分数  解吸气
收稿时间:2004-04-06
修稿时间:2004-09-20

Experimental study on separation of oxygen and argon by carbon molecular sieves
CUI Hongshe,LIU Yingshu,LIU Wenhai,YUE Kai,ZHANG Dexin. Experimental study on separation of oxygen and argon by carbon molecular sieves[J]. Journal of University of Science and Technology Beijing, 2005, 27(4): 493-496
Authors:CUI Hongshe  LIU Yingshu  LIU Wenhai  YUE Kai  ZHANG Dexin
Abstract:
The experimental apparatus for the separation of oxygen and argon was established based on the kinetic adsorption of carbon molecular sieves. The effects of PSA cycle, rinse-ratio and adsorption duration on the performance of adsorption processes were investigated. The experimental results show that to incorporate the rinse step can increase greatly the concentration of oxygen in desorbed gas. For producing high purity oxygen, the optimum values of the rinse-ratio and adsorption duration should be about 0.4 and 60 s respectively. Under this condition, the oxygen purity up to 99.4% is obtained for the 42% recovery with the feed gas mixture of 95% oxygen and 5% argon.
Keywords:carbon molecular sieve   separation of oxygen and argon   PSA   rinse-ratio   high purity oxygen
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