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| HPLC阀切换及梯度洗提法研究H2NS^—4在液氨中的分解 | |
| 引用本文： | 周丹红 冯卓夫. HPLC阀切换及梯度洗提法研究H2NS^—4在液氨中的分解[J]. 辽宁师范大学学报(自然科学版), 1997, 20(2): 135-138 |
| 作者姓名： | 周丹红 冯卓夫 |
| 作者单位： | 辽宁师范大学化学系 |
| 基金项目： | 辽宁省教委博士启动基金 |
| 摘 要： | 采用ＨＰＬＣ的阀切换二次分离及梯度洗提技术对硫－氨溶液中的主要成分Ｈ２ＮＳ＾－４进行研究，证明其在液氨中的分解是经过中间过渡产物Ｓ３Ｎ和Ｓ３然后生成Ｓ４Ｎ最终达到平衡。 |
| 关 键 词： | 硫－氨溶液 H2NS^－4 分解 HPLC 阀切换 梯度洗提 |
STUDY ON THE DECOMPOSITION REACTON OF H 2NS - 4 IN SULPHUR AMMONIA SOLUTION BY HPLC VALVE SWITCHING AND GRADIENT ELUTION TECHNIQUES |
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| Zhou Danhong Feng Zhuofu Zhang Wenwei. STUDY ON THE DECOMPOSITION REACTON OF H 2NS - 4 IN SULPHUR AMMONIA SOLUTION BY HPLC VALVE SWITCHING AND GRADIENT ELUTION TECHNIQUES[J]. Journal of Liaoning Normal University(Natural Science Edition), 1997, 20(2): 135-138 | |
| Authors: | Zhou Danhong Feng Zhuofu Zhang Wenwei |
| Abstract: | Decomposition reactions of H 2NS - 4 in sulfur ammonia solution were studied through HPLC valve switching and gradient eluation technique,it was proved that the decomposition of H 2NS - 4 in the solution was/through intermediates S 3N - and S - 3 and S 4N - was conseguently produced and finally reached equilibrium. |
| Keywords: | Sulfur ammonia solutions Descomposition of H 2NS - 4 component Anion exchange HPLC Valve switching for peak cutting Gradient elution |
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