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聚乙烯亚胺对ZnO纳米线阵列膜的形貌和光电性能的影响
引用本文:杨伟光,万发荣,姜春华,陈思维.聚乙烯亚胺对ZnO纳米线阵列膜的形貌和光电性能的影响[J].北京科技大学学报,2010,32(1).
作者姓名:杨伟光  万发荣  姜春华  陈思维
作者单位:1. 北京科技大学材料科学与工程学院,北京,100083
2. 北京科技大学材料科学与工程学院,北京100083;北京市新能源材料与技术重点实验室,北京,100083
3. 彩虹集团公司技术中心,北京,100085
摘    要:采用X射线衍射仪、投射电镜仪和扫描电镜仪等测试手段,系统地研究了不同聚乙烯亚胺(PEI)浓度对ZnO纳米线阵列膜的形貌、线密度和尺寸的影响及ZnO纳米线阵列膜的光电性能.研究结果表明,在PEI浓度从3.2 mmol.L-1变化到9.3 mmol.L-1所制备的所有ZnO纳米线阵列膜中,使用7.3 mmol.L-1PEI浓度合成的ZnO纳米线阵列膜,制成染料敏化太阳能电池后获得0.66%的最高的光电转换效率.

关 键 词:纳米线阵列  光阳极  染料敏化太阳能电池  光电性能  

Effect of polyethylenimine on morphology and photovoltaic property of ZnO nanowire array films
YANG Wei-guang,WAN Fa-rong,JIANG Chun-hua,CHEN Si-wei.Effect of polyethylenimine on morphology and photovoltaic property of ZnO nanowire array films[J].Journal of University of Science and Technology Beijing,2010,32(1).
Authors:YANG Wei-guang  WAN Fa-rong  JIANG Chun-hua  CHEN Si-wei
Abstract:The effect of polyethylenimine (PEI) concentration on the morphology, wire density and size of ZnO nanowire arrays was systematically studied by X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscope (SEM). The photovoltaic properties of ZnO nanowire array films were also investigated. It is demonstrated that, for a ZnO nanowire array film obtained from 7.3 mmol·L~(-1) PEI, an energy conversion efficiency of about 0.66% was obtained, which is the highest for ZnO nanowire array films prepared with different PEI concentrations from 3.2 mmol·L~(-1) to 9.3 mmol·L~(-1).
Keywords:nanowire arrays  photoanode  dye-sensitized solar cells  photovoltaic property  
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