| KF-Al2O3试剂在Michael加成反应中的新应用 |
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| 引用本文： | 于法锋,黄初升,崔建国.KF-Al2O3试剂在Michael加成反应中的新应用[J].广西师范学院学报(自然科学版),2002,19(4):5-7. |
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| 作者姓名： | 于法锋 黄初升 崔建国 |
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| 作者单位： | 广西师范学院,化学系,广西,南宁,530001 |
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| 摘 要： | 芳亚甲基丙二腈和硝基甲烷在KF-Al2O3的作用下发生双Michael加成，继而发生环化反应生成2-氨基-1，3，3-三氰基-5-硝基-4，6-二芳基环己烯，该反应的研究为此类化合物的合成提供了一种方便的方法。
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| 关 键 词： | KF-Al2O3 Michael加成 芳亚甲基丙二腈 2-氨基-1，3，3-三氰基-5-硝基-4，6-二芳基环己烯 |
| 文章编号： | 1002-8743(2002)04-0005-03 |
| 修稿时间： | 2002年6月8日 |
A New Application of KF-Al2O3 in Michael Addition Reaction |
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| YU Fa-feng,HUANG Chu-sheng,CUI Jian-guo.A New Application of KF-Al2O3 in Michael Addition Reaction[J].Journal of Guangxi Teachers Education University:Natural Science Edition,2002,19(4):5-7. |
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| Authors: | YU Fa-feng HUANG Chu-sheng CUI Jian-guo |
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| Abstract: | Arylmethylidene-malononitrile and nitromethyane generated Michael addition reaction under the condition of KF-Al 2O 3 as catalyst.Then 2-amino-1,3,3-trinitrile-5-nitryl-4,6-diarylcyclohexene was synthesized by cyclization of the Michael addition product. A usable method of synthesized this kind of compounds was obtained by researching this reaction. |
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| Keywords: | KF-Al 2O 3 Michael addition reaction aryl Methylidene-malononitrile 2-amino-1 3 3-trinitrile-5-nitryl-4 6-diarylcyclohexene |
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