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等静压和温度作用下Pb(Zr,Sn,Ti)O3陶瓷的介电性能研究
引用本文:郑曙光,徐卓,冯玉军,姚熹.等静压和温度作用下Pb(Zr,Sn,Ti)O3陶瓷的介电性能研究[J].西安交通大学学报,2002,36(10):1004-1007.
作者姓名:郑曙光  徐卓  冯玉军  姚熹
作者单位:西安交通大学电子陶瓷与器件教育部重点实验室,710049,西安
摘    要:对反铁电-铁电相界附近的Nb掺杂Pb(Zr,Sn,Ti)O3陶瓷,采用2GPa等静压装置测试了其在不同等静压力下的介电温度性能,分析了各种介电异常,发现了精细的相变特性,指出随着温度升高,在较低的等静压范围内发生反铁电-铁电-顺电相变,而在较高的等静压范围内发生反铁电-顺电相变,其中,铁电相分为微弱频率弥散的弛豫型铁电相和正常铁电相两个不同的介电性能区域,最后,得到了该组分材料的温度-等静压相图。

关 键 词:Pb(Zr  Sn  Ti)O3陶瓷  反铁电-铁电陶瓷  介电性能  反铁电-铁电-顺电相变  等静压  介电温度  反铁电-顺电相变
文章编号:0253-987X(2002)10-1004-04
修稿时间:2002年1月23日

Study on the Dielectric Properties of Pb(Zr,Sn, Ti)O3 Ceramics under Hydrostatic Pressure and Temperature
Zheng Shuguang,Xu Zhuo,Feng Yujun,Yao Xi.Study on the Dielectric Properties of Pb(Zr,Sn, Ti)O3 Ceramics under Hydrostatic Pressure and Temperature[J].Journal of Xi'an Jiaotong University,2002,36(10):1004-1007.
Authors:Zheng Shuguang  Xu Zhuo  Feng Yujun  Yao Xi
Abstract:The temperature dependenices and the hydrostatic pressure dependencies of the dielectric properties of Nb-doped Pb (Zr,Sn, Ti)O3 ceramics were measured. The abnormity of the dielectric properties and the phase transition properties of the ceramics in the vicinity of the anti ferroelectric(AFE)-ferroelectric (FE) phase boundary were studied. It was found that with increasing temperature, an AFE FE PE(paraelectric) phase transition at low hydrostatic pressure and an AFE PE one at higher pressure occurred. The FE phase consisted two parts with different dielectric properties:one was norma l FE phase, the other was relaxor FE phase with weak frequency dispersion. And t he two dimension phase diagram of temperature and hydrostatic pressure of this sample is obtained.
Keywords:antiferroelectric  ferroelec tric ceramics  dielectric properties  phase transition  hy    drostatic pressure
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