| Keggin结构过氧钛钨硅杂多配合物~(183)WNMR谱的研究 |
| |
| 引用本文： | 单秋杰,陈华君,单英军.Keggin结构过氧钛钨硅杂多配合物~(183)WNMR谱的研究[J].高师理科学刊,1997(2). |
| |
| 作者姓名： | 单秋杰 陈华君 单英军 |
| |
| 作者单位： | 齐齐哈尔车辆厂一中 |
| |
| 摘 要： | 合成了Keggin结构一，三取代过氧铁钨硅杂多配合物，这两种化合物是：α－K6［SiW11（Tio2）O39］·12H2O和α－K9H［SiW9（TiO2）O39］·12H2O，并对183WNMR谱进行了指认，从而确定了2种过氧杂多配合物的基本结构．
|
| 关 键 词： | Keggin结构 过氧钛钨硅杂多配合物 ~(183)WNMR |
Studies on ~(183)WNMR Spectra of Peroxotitanium Tungstosilicates Heteropoly Complexs with Keggin Structure |
| |
| Shan Qiujie, Chen Huajun, Shan Yingjun.Studies on ~(183)WNMR Spectra of Peroxotitanium Tungstosilicates Heteropoly Complexs with Keggin Structure[J].Journal of Science of Teachers＇College and University,1997(2). |
| |
| Authors: | Shan Qiujie Chen Huajun Shan Yingjun |
| |
| Institution: | Shan Qiujie; Chen Huajun; Shan Yingjun (Department of Chemistry ) (No.1 Middle School of Qiqihar Rolling Stock Works) |
| |
| Abstract: | In this paper heteropoly complexes of peroxotitanium mono-substituted and tri -substituted with Keggin structure: α- K5SiW11(TiO2)O39·12H2O and α-K9HSiW9(TiO3)O39· 12H2O Have been synthesized. The spectra of 183WNMR have been assigned so that two basic structures of peroxotitanium heteropoly complexes are determined. |
| |
| Keywords: | Keggin structure Peroxotitanium tungstosilicates heteropoly complex ~(183)WNMR |
| 本文献已被 CNKI 等数据库收录！ |
