| H_4PMo_(11)VO_(40)催化氧化2-甲基萘制备甲萘醌 |
| |
| 引用本文： | 靳会杰,韩志慧,廉红蕾,雒廷亮,江振西,刘国际.H_4PMo_(11)VO_(40)催化氧化2-甲基萘制备甲萘醌[J].河南师范大学学报(自然科学版),2010,38(6). |
| |
| 作者姓名： | 靳会杰 韩志慧 廉红蕾 雒廷亮 江振西 刘国际 |
| |
| 基金项目： | 河南省教育厅自然科学研究资助计划项目 |
| |
| 摘 要： | 以磷钼钒杂多酸H4PMo11V1O40为催化剂、乙酸为溶剂,用双氧水氧化2-甲基萘制备2-甲基萘醌.实验表明:H4PMo11V1O40具有一定的催化活性.通过正交试验和单因素试验考察了催化剂用量、乙酸用量、双氧水用量、反应时间、反应温度等对收率的影响,获得较佳的合成条件:杂多酸∶2-MN(质量比)=7%,乙酸∶2-MN(质量比)=10.5∶1,双氧水∶2-甲基萘(摩尔比)=4.2∶1,较适宜的温度为40~50℃,反应时间为30 min.
|
| 关 键 词： | 杂多酸 H4PMo11VO40 过氧化氢 2-甲基萘 2-甲基萘醌 催化氧化 |
H4PMo11VO40 Catalytic Oxidation 2-methyl Naphtalene Preparation 2-methyl-1,4-naphthoquinone |
| |
| JIN Hui-jie,HAN Zhi-hui,LIAN Hong-lei,LUO Ting-liang,JIANG Zhen-xi,LIU Guo-ji.H4PMo11VO40 Catalytic Oxidation 2-methyl Naphtalene Preparation 2-methyl-1,4-naphthoquinone[J].Journal of Henan Normal University(Natural Science),2010,38(6). |
| |
| Authors: | JIN Hui-jie HAN Zhi-hui LIAN Hong-lei LUO Ting-liang JIANG Zhen-xi LIU Guo-ji |
| |
| Abstract: | In this paper,2-methylnaphtalene(2-MN) is oxidized into 2-methyl-l,4-naphthoquinone(2-MNQ,menadione) by H2O2 using acetic acid as solvent in the presence of H4PMo11V1O40 as catalyst.The results indicate that H4PMo11V1O40 catalyze producing menadione.The effect of quantity of catalysts,acetic acid and H2O2,reaction temperature and reaction time on menadione yield is discussed.The optimum reaction condition is that: the quantity of catalyst is 7% of 2-MN,mass ratio of acetate to 2-MN is 10.5∶1,mol ratio of H2O2 to 2-MN is 4.2∶1,the suitable reaction temperature is 40-50 ℃ and the reaction time is 30 min. |
| |
| Keywords: | heteronoly acid H4PMo11V1O40 Hydrogen peroxide 2-methyl naphtalene 2-methyl-1 4-naphthoquinone catalytic oxidation |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
