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混晶纳米TiO2光催化性能及混晶相间的机理研究
引用本文:张慧,王洪涛,金凤,胡向阳.混晶纳米TiO2光催化性能及混晶相间的机理研究[J].阜阳师范学院学报(自然科学版),2011,28(1):53-56.
作者姓名:张慧  王洪涛  金凤  胡向阳
作者单位:张慧,金凤,胡向阳,ZHANG Hui,JIN Feng,HU Xiang-yang(阜阳师范学院,化学化工学院,安徽,阜阳,236041);王洪涛,WANG Hong-tao(阜阳师范学院,化学化工学院,安徽,阜阳,236041;苏州大学,材料与化学化工学院,江苏,苏州,215123)
基金项目:安徽青年教师"资助计划",阜阳师范学院科学研究项目
摘    要:采用溶胶-凝胶法制备混晶纳米TiO2和珍珠岩负载纳米TiO2混晶催化剂,以XRD、SEM、UV-vis DRS和电化学方法对样品进行表征.结果表明,晶型调节剂的含量对混晶中金红石和锐钛矿相TiO2的比率有较大的影响;对于负载型纳米TiO2催化剂,混晶比影响催化剂的光催化降解效率.并讨论了混晶的光催化机理.

关 键 词:纳米TiO2  混晶  光催化  混晶效应

Studies on the photocatalytic activity and synergism among phases of the mixed crystal nano-TiO_2
ZHANG Hui,WANG Hong-tao,JIN Feng,HU Xiang-yang.Studies on the photocatalytic activity and synergism among phases of the mixed crystal nano-TiO_2[J].Journal of Fuyang Teachers College:Natural Science,2011,28(1):53-56.
Authors:ZHANG Hui  WANG Hong-tao  JIN Feng  HU Xiang-yang
Institution:ZHANG Hui1,WANG Hong-tao1,2,JIN Feng1,HU Xiang-yang1(School of Chemistry and Chemical Engineering,Fuyang Teachers College,Fuyang Anhui 236041,China,School of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou Jiangsu 215123,China)
Abstract:Mixed phase nano-TiO2 and mixed phase nano-TiO2/EP were prepared by Sol-gel method and the content of rutile in the mixed phase was controllable by doping hexylene glycol(HG).The catalysts are characterized by XRD,UV-visible DRS and electrochemistry method.The results show that the ratio of R/A phase in mixed crystal is fixed by regulator HG.It is different in degradation effect of dye when the ratio of mixed crystal in supported nano-TiO2 is changed.This article also investgates the photocatalytic mechanis...
Keywords:nano-TiO2  mixed phase  photocatalysis  mixed crystal effect  
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