| 聚乙二醇与PdCl_2催化端烯衍生物芳基化研究 |
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| 引用本文： | 韩建荣,康汝洪,甄小丽.聚乙二醇与PdCl_2催化端烯衍生物芳基化研究[J].河北师范大学学报(自然科学版),1998(3). |
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| 作者姓名： | 韩建荣 康汝洪 甄小丽 |
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| 作者单位： | 河北师范大学化学系!050016，石家庄(韩建荣，康汝洪)，河北科技大学基础部!050018，石家庄(甄小丽) |
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| 摘 要： | 研究了聚乙二醇与PdCl_2催化碘苯与端烯衍生物芳基化反应．实验证明聚乙二醇有显著催化作用，产品具有极好的区域和立体选择性．
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| 关 键 词： | 聚乙二醇 二氯化钯 芳基化反应 偶联反应 立体选择性 |
Studies on Regio and Stereoselectivities of Arylation of Terminal Olefinic Derivatives Catalyzed by Poly (Ethyleneglycol)and PdCl_2 |
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| Han Jianrong, Kang Ruhong, Zhen Xiaoli.Studies on Regio and Stereoselectivities of Arylation of Terminal Olefinic Derivatives Catalyzed by Poly (Ethyleneglycol)and PdCl_2[J].Journal of Hebei Normal University,1998(3). |
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| Authors: | Han Jianrong Kang Ruhong Zhen Xiaoli |
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| Abstract: | Arylation reaction of iodobenzene with terminal olefinic derivatives arestudied in presence of poly (ethyleneglycol) (PEG)and PdCI,. The experiment provedthat PEG has obviously catalytic action and products have good regio and stereoselectlvity. |
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| Keywords: | poly(ethyleneglycol) palladium dichlorides arylation reaction couping reaction stereoselectivity |
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