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High efficiency D-A structured luminogen with aggregation-induced emission and mechanochromic characteristics
Authors:YaWei Lu  YeQiang Tan  YongYang Gong  Hong Li  WangZhang Yuan  YongMing Zhang  Ben Zhong Tang
Institution:1. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China
2. Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, China
3. Department of Chemistry, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China
Abstract:A novel luminogen, CZ2TPAN, with typical D-A architecture was obtained. It shows intramolecular charge transfer and aggregation-induced emission characteristics with high solid-state efficiency of 65.3%. Moreover, it exhibits reversible mechanochromic behavior between crystalline and amorphous states with remarkable emission color change from green (504 nm) to yellow (545 nm).
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