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| 云杉红翅小蠹信息素Seudenone和(±)-Seudenol的简便合成 | |
| 引用本文： | 殷彩霞,高竹林,刘复初,李霁良,张甦. 云杉红翅小蠹信息素Seudenone和(±)-Seudenol的简便合成[J]. 云南大学学报(自然科学版), 2000, 22(6): 443-445 |
| 作者姓名： | 殷彩霞 高竹林 刘复初 李霁良 张甦 |
| 作者单位： | 云南大学,应用化学系,云南,昆明,650091 |
| 摘 要： | 3-甲基环己-2-烯-1-酮(Seudenone)是云杉红翅小蠹的抑制信息素,3-甲基环己-2-烯-1-醇(±-Seudenol)却是一种聚集信息素.本合成利用乙酰乙酸乙酯和多聚甲醛为原料,通过缩合、水解脱羧和区域选择性还原三步反应合成了两个所需产物. |
| 关 键 词： | 云杉红翅小蠹 抑制信息素 聚集信息素 合成 |
A Facile Synthesis of Seudenone and Racemic Seudenol |
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| YIN Cai-xia,GAO Zhu-lin,LIU Fu-chu,LI Ji-liang,ZHANG Shu. A Facile Synthesis of Seudenone and Racemic Seudenol[J]. Journal of Yunnan University(Natural Sciences), 2000, 22(6): 443-445 | |
| Authors: | YIN Cai-xia GAO Zhu-lin LIU Fu-chu LI Ji-liang ZHANG Shu |
| Abstract: | Seudenone (3-methylcyclohex-2-en-1-one) is an antiaggregation pheromone of Douglas fir beetle,Dendroctonus pseudotsugae.Seudenol (3-methyl cyclohex-2-en-1-ol) is an aggregation pheromone of Douglas fir beetle,Dendroctonus pseudotsugae.The synthesis employed ethyl acetoacetate and paraformaldehyde as starting materials.The route of synthesis was carried out by 3 steps:condensation,hydrolysis and decaxboxylation,and regioselective reduction. |
| Keywords: | seudenone Seudenol pheromone synthesis |
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