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PBS对PLA/凹凸棒石黏土复合材料性能的影响
引用本文:卢玉献,徐惠,程晓春,金叶玲,吴洁.PBS对PLA/凹凸棒石黏土复合材料性能的影响[J].甘肃科学学报,2012,24(2):27-30.
作者姓名:卢玉献  徐惠  程晓春  金叶玲  吴洁
作者单位:1. 兰州理工大学石油化工学院,甘肃兰州,730050
2. 淮阴工学院生命科学与化学工程学院,江苏省凹土资源利用重点实验室,江苏淮安223003
基金项目:国家自然科学基金,江苏省自然科学基金,江苏省工业支撑计划项目
摘    要:在140℃,氮气保护的条件下,使L-丙交酯开环与凹凸棒石黏土(AT)表面上的(Si-OH)发生反应,生成的低分子量聚乳酸接枝到经过处理的凹凸棒石黏土上,然后将接枝凹凸棒石黏土与聚乳酸(PLA)景丁二酸丁二醇酯(PBS)进行熔融共混,制备PLA/PBS/凹凸棒石黏土(AT)复合材料.通过FTIR、SEM、力学性能测试及维卡软化测试仪对复合材料进行分析和袁征.实验结果表明,凹凸棒石黏土的最佳加入量为1.5%;PBS的加入可以大大提高PLA的韧性,当加入量为25%时,综合力学性能最佳.

关 键 词:聚乳酸  聚丁二酸丁二醇酯  凹凸棒石黏土  复合材料

The Influence of PBS on the Properties of PLA/Attapulgite Clay Composite
LU Yu-xian , XU Hui , CHENG Xiao-chun , JIN Ye-ling , WU Jie.The Influence of PBS on the Properties of PLA/Attapulgite Clay Composite[J].Journal of Gansu Sciences,2012,24(2):27-30.
Authors:LU Yu-xian  XU Hui  CHENG Xiao-chun  JIN Ye-ling  WU Jie
Institution:1.College of Petrochemical Technology,Lanzhou University of Science and Technology,Lanzhou 730050,China; 2.School of Life Science and Chemical Engineering,Huaiyin Institute of Technology,Key Laboratory for Palygorskite Science and Applied Technology of Jiangsu Province,Huaian 223003,China)
Abstract:The L-lactide was reacted with Si-OH on attapulgite clay surface via a ring-opening under the protection of nitrogen at 140 ℃ to produce polylactic acid oligomers,which were grafted onto the treated attapulgite clay(AT),and then they melted blending with polylactic acid(PLA) and poly(butylene succinate)(PBS) to obtain PLA/PBS/attapulgite clay(AT) composites.They were analysed and characterized by means of FTIR,SEM,mechanical property testing and Vicat softening tester.The results showed that the best content of attapulgite was 1.5%.The addition of PBS could greatly improve the toughness of PLA;for best mechanical properties,the optimal amount was 25%.
Keywords:PLA  PBS  attapulgite clay  composite
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