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| 新型光敏剂Corrole激发态动力学研究 | |
| 引用本文： | 王雪,封昌盛,何霜,史蕾,张蕾,刘海洋,王惠,计亮年.新型光敏剂Corrole激发态动力学研究[J].中山大学学报(自然科学版),2014,53(1). |
| 作者姓名： | 王雪 封昌盛 何霜 史蕾 张蕾 刘海洋 王惠 计亮年 |
| 作者单位： | 1.中山大学理工学院//光电材料与技术国家重点实验室，广东 广州 510275 2.华南理工大学化学系，广东 广州 510641 3.中山大学化学与化学工程学院，广东 广州 510275 |
| 基金项目： | 国家自然科学基金资助项目(61178037,11004256,21171057);国家重点基础研究发展计划973资助项目(2013CB922403);中山大学光电材料与技术国家重点实验室开放课题资助项目 |
| 摘 要： | 通过采用稳态和飞秒荧光上转换的激光光谱技术,测量了三种新型光敏剂镓Corrole:F10-Ga、P-OHGa及P-P-Ga分别在非极性溶剂甲苯和极性溶剂乙醇中的吸收和发光过程。结果表明,苯环上的单羟基与吩噻嗪取代对镓Corrole的吸收和发光性能影响不明显。而三种镓Corrole在乙醇中的B带吸收峰都明显蓝移、荧光峰则明显红移、荧光量子产率减小,而且激发态弛豫过程S2→S1明显比在甲苯中慢。 |
| 关 键 词： | Corrole 飞秒荧光上转换技术 超快动力学 |
| 收稿时间： | 2013-04-03; |
The Studies on Ultrafast Dynamics of Three Kinds of Corroles |
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| WANG Xue FENG Changsheng,HE Shuang,SHI Lei,ZHANG Lei,LIU Haiyang,WANG Hui,JI Liangnian.The Studies on Ultrafast Dynamics of Three Kinds of Corroles[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2014,53(1). | |
| Authors: | WANG Xue FENG Changsheng HE Shuang SHI Lei ZHANG Lei LIU Haiyang WANG Hui JI Liangnian |
| Institution: | 1.State Key Laboratory of Optoelectronics Materials and Technologies, Sun Yat-sen University, Guangzhou 510275, China; 2.Department of Chemistry, South China University of Technology, Guangzhou 510641, China; 3.School of Chemistry and Chemical Engineering, Sun Yat sen University, Guangzhou 510275, China |
| Abstract: | The steady state spectroscopy and the femtosceond fluorescence upconversion in three kinds of Ga Corroles in toluene and ethanol solvent have been studied. The results show that the effect of the hydroxyl and PTZ substitution on the properties of those Corroles is not significant. In contrast, the blue shifts in absorption spectra, the red shifts in emission spectra and the reduction in fluorescence quantum yield observed when ethanol replaces toluene as a solvent. Moreover, the ultrafast dynamics S2→S1 of those Corroles varied significantly in different solvents. Evidently, solvent has a significant effect on those Corroles-energy level structure and optical properties. |
| Keywords: | Corroles femtosecond fluorescence upconversion technology ultrafast dynamics |
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