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SOFC电解质材料La0.8Sr0.2Ga0.8-xMg0.2CoxO3-δ的制备及性能#br#
引用本文:张国栋,王欢,王利行,常笑鹏,宋浩冉,骆泽阳,徐培,王德军.SOFC电解质材料La0.8Sr0.2Ga0.8-xMg0.2CoxO3-δ的制备及性能#br#[J].吉林大学学报(理学版),2002,58(1):162-165.
作者姓名:张国栋  王欢  王利行  常笑鹏  宋浩冉  骆泽阳  徐培  王德军
作者单位:1. 长春大学 理学院材料设计与量子模拟重点实验室, 长春 130022; 
2. 长春大学 研究生院, 长春 130022
摘    要:利用甘氨酸 硝酸盐燃烧法制备不同浓度Co掺杂的La0.8Sr0.2Ga0.8-xMg0.2CoxO3-δ固体氧化物燃料电池电解质材料, 并对其晶体结构、 形貌以及电学性能进行表征. 结果表明: 随着Co掺杂量的增加, 样品无明显杂相峰, 其谱峰略向小角度一侧移动, 晶胞体积略增大,  平均粒径逐渐减小; Co掺杂对电导率影响显著, 晶粒电导率是导致样品总电导率升高的主要因素.

关 键 词:固体氧化物燃料电池    电解质    甘氨酸  硝酸盐燃烧法    晶胞体积  
收稿时间:2019-07-09

Preparation and Performance of La0.8Sr0.2Ga0.8-xMg0.2CoxO3-δElectrolytes for SOFC#br#
ZHANG Guodong,WANG Huan,WANG Lihang,CHANG Xiaopeng,SONG Haoran,LUO Zeyang,XU Pei,WANG Dejun.Preparation and Performance of La0.8Sr0.2Ga0.8-xMg0.2CoxO3-δElectrolytes for SOFC#br#[J].Journal of Jilin University: Sci Ed,2002,58(1):162-165.
Authors:ZHANG Guodong  WANG Huan  WANG Lihang  CHANG Xiaopeng  SONG Haoran  LUO Zeyang  XU Pei  WANG Dejun
Institution:1. Key Laboratory of Materials Design and Quantum Simulation, College of Science, Changchun University, Changchun 130022, China; 2. Graduate College, Changchun University, Changchun 130022, China
Abstract:TheLa0.8Sr0.2Ga0.8-xMg0.2CoxO3-δ electrolytes for solid oxide fuel cell (SOFC) with different concentrations ofCo were prepared by glycine nitrate combustion method, and the crystal structure, morphology and electrical properties were characterized. The results show that, with the increase of Co doping, there is no obvious heterophase peak in the sample, the spectral peaks shift slightly to the side of small angle, the cell volume increases slightly, and the average partical size decre ases gradually. Co doping has a siginificant effect on the conductivity, and the grain conductivity is the key factor to increase the total conductivity of the sample.
Keywords:solid oxide fuel cell (SOFC)  electrolyte  glycine nitrate combustion method  cell volume  
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