| PMNBP缩氨基酸席夫碱配合物的合成、表征和晶体结构 |
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| 引用本文： | 孙晨,张欣.PMNBP缩氨基酸席夫碱配合物的合成、表征和晶体结构[J].天津师范大学学报(自然科学版),2012,32(4):61-66. |
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| 作者姓名： | 孙晨 张欣 |
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| 作者单位： | 天津师范大学化学学院,天津,300387 |
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| 基金项目： | 国家自然科学基金资助项目 |
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| 摘 要： | 合成1-苯基-3-甲基-4-对硝基苯甲酰基-5-吡唑啉酮（PMNBP）缩苯丙氨酸甲酯席夫碱及其Ni（Ⅱ）、Co（Ⅱ）金属配合物,并对合成的配合物进行红外光谱的表征.利用X射线单晶衍射法测定配合物的晶体结构,结果表明二者均为六配位同构配合物.
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| 关 键 词： | 席夫碱 配合物 合成 红外光谱法 X射线单晶衍射法 晶体结构 |
Synthesis, characterization and crystal structure of metal complex from amino acid Schiff base of PMNBP |
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| SUN Chen
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ZHANG Xin.Synthesis, characterization and crystal structure of metal complex from amino acid Schiff base of PMNBP[J].Journal of Tianjin Normal University(Natural Science Edition),2012,32(4):61-66. |
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| Authors: | SUN Chen ZHANG Xin |
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| Institution: | ( College of Chemistry , Tianjin Normal University , Tianjin 300387 , China ) |
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| Abstract: | A kind of Schiff base derived from 1-phenyl-3-methyl-4（ p-nitrobenzoyl ） -5-pyrazolone （ PMNBP ） with L-phenylalanine methyl ester and its metal （ Ni 2＋, Co 2＋ ） complexes were synthesized.IR was performed. The crystal structures were measured through X-ray diffraction, and the sixcoordinate isomorphism of the two complexes were determined. |
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| Keywords: | Schiff base complex synthesize IR X-ray diffraction crystal structure |
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