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用于紫外光固化涂料的羧基化环氧丙烯酸酯水分散性研究
引用本文:梁宗军,史宜望,沈亚,胡和丰. 用于紫外光固化涂料的羧基化环氧丙烯酸酯水分散性研究[J]. 上海大学学报(自然科学版), 2005, 11(3): 303-306
作者姓名:梁宗军  史宜望  沈亚  胡和丰
作者单位:上海大学,材料科学与工程学院,上海,201800;上海大学,材料科学与工程学院,上海,201800;上海大学,材料科学与工程学院,上海,201800;上海大学,材料科学与工程学院,上海,201800
摘    要:根据亲水亲油平衡值(HLB)设计了以马来酸酐改性环氧丙烯酸酯的方案,合成了具有良好水分散性的羧基化环氧丙烯酸酯树脂.用电导率法表征了羧基化环氧丙烯酸酯的水分散性,研究了羧基化程度、中和程度对树脂水分散性的影响;配制了水性紫外光固化涂料,所得涂膜性能良好.

关 键 词:水分散性  环氧丙烯酸酯  马来酸酐  电导率  亲水亲油平衡值  紫外光固化
文章编号:1007-2861(2005)03-0303-04
修稿时间:2004-03-22

Water-Dispersing Properties of Carboxylated Epoxy Acrylate for UV-Curable Coating
LIANG Zong-jun,SHI Yi-wang,Shen Ya,HU He-feng. Water-Dispersing Properties of Carboxylated Epoxy Acrylate for UV-Curable Coating[J]. Journal of Shanghai University(Natural Science), 2005, 11(3): 303-306
Authors:LIANG Zong-jun  SHI Yi-wang  Shen Ya  HU He-feng
Abstract:Based on the principle of HLB, a scheme of epoxy acrylate modified with maleic anhydride was designed, and carboxylated acrylate epoxy with good water dispersity was synthesized successfully. Water dispersion of carboxylated acrylate epoxy was characterized with specific conductivity. The effects of carboxylation and neutralization on specific conductivity were studied too. Water-borne UV-curable coatings without VOC were developed and were cured into film. The properties of the film are good.
Keywords:water-dispersion  epoxy acrylate  maleic anhydride  specific conductivity  HLB  UV-curable
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