| Synthesis, characterization and properties of ruthenium-substituted polyoxometallic acid H_6Ru(H_2O)FeW_(11)O_(39)·18H_2O with Keggin structure |
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| 引用本文： | XU ShengXian ,,WU XueFei ,WU QingYin & YAN WenFu Department of Chemistry,Zhejiang University,Hangzhou ,China, School of Chemistry , Chemical Engineering,Jiangxi Science , Technology Teachers’ College,Nanchang , State Key Laboratory of Inorganic Synthesis , Preparative Chemistry,Jilin University,Changchun ,China Received October ,,accepted January ,.Synthesis, characterization and properties of ruthenium-substituted polyoxometallic acid H_6Ru(H_2O)FeW_(11)O_(39)·18H_2O with Keggin structure[J].中国科学通报(英文版),2011,56(25):2679-2682. |
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| 作者姓名： | XU ShengXian WU XueFei WU QingYin & YAN WenFu |
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| 作者单位： | XU ShengXian 1,2,WU XueFei 1,WU QingYin 1& YAN WenFu 3 1 Department of Chemistry,Zhejiang University,Hangzhou 310027,China,2 School of Chemistry and Chemical Engineering,Jiangxi Science and Technology Teachers’ College,Nanchang 330013,3 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun 130012,China Received October 28,2010,accepted January 7,2011 |
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| 基金项目： | supported by the National Natural Science Foundation of China (21071124); the Foundation of Jiangxi Educational Committee (GJJ09310); the Foundation of the State Key Laboratory of Inorganic Synthesis; Preparative Chemistry of Jilin University (2010-16) |
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| 摘 要： | The ruthenium-substituted polyoxometallic acid H6 Ru(H2O)FeW 11O39 ]·18H2O was synthesized by stepwise acidification and stepwise addition of solutions of the component elements, and an ion-exchange-cooling method. The product was characterized using inductively coupled plasma spectrometry (ICP), Infrared Spectroscopy (IR), Ultraviolet Spectroscopy (UV), and X-ray diffraction (XRD). The results show that this complex has the Keggin structure. The determination of the thermal stability and proton conductivi...
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| 关 键 词： | Keggin结构 H2O 电感耦合等离子体光谱法 合成 性质 表征 电化学阻抗谱 钌 |
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