| 3,6-二对乙氧基苯基-1,2,4-三唑[3,4-b]1,2,4-三唑并1,3,4-噻二唑的合成 |
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| 引用本文： | 赵珅,邢锦娟,刘琳.3,6-二对乙氧基苯基-1,2,4-三唑[3,4-b]1,2,4-三唑并1,3,4-噻二唑的合成[J].渤海大学学报(自然科学版),2007,28(2):126-128. |
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| 作者姓名： | 赵珅 邢锦娟 刘琳 |
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| 作者单位： | 1. 渤海大学,应用化学省级重点实验室,辽宁,锦州,121013
2. 中国科学院金属研究所,金属腐蚀与防护国家重点实验室,辽宁,沈阳,110016 |
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| 基金项目： | 教育部科学技术研究重点项目;辽宁省教育厅科学计划项目 |
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| 摘 要： | 以2，5-二巯基-1，3，4-噻二唑为原料，与水合肼缩合，生成2，5-二肼基-1，3，4-噻二唑。2，5-二肼基-1，3，4-噻二唑与对乙氧基苯四酰氯反应，再以POCl3为环合剂环合酰肼基-1，3，4-噻二唑，得到3，6-二对乙氧基苯基-1，2，4-三唑3，4-b]1，2，4-三唑并1，3，4-噻二唑，合成的此化合物未见报道，其结构通过元素分析、红光光谱、核磁共振氢谱和质谱予以证实。
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| 关 键 词： | 2 5-二肼基-1 3 4-噻二唑 闭环 合成- |
| 文章编号： | 1673-0569（2007）02-0126-03 |
| 修稿时间： | 2007-03-12 |
Synthesis of 3,6-bi-p-ethoxy-phenyl-1,2,4-triazolo [3,4-b ]-1,2,4-triazolo-1,3,4-thiadiazole |
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| ZHAO Shen,XING Jin-juan,LIU Lin.Synthesis of 3,6-bi-p-ethoxy-phenyl-1,2,4-triazolo [3,4-b ]-1,2,4-triazolo-1,3,4-thiadiazole[J].Journal of Bohai University:Natural Science Edition,2007,28(2):126-128. |
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| Authors: | ZHAO Shen XING Jin-juan LIU Lin |
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| Institution: | 1. Provincial Key Laboratory for Applied Chemis try , Bohai University, Jinzhou 121013, China ; 2. State Key Laboratory for Corrosion and Protection, Institute of Metal Research, The Chinese Academy of Sciences, Shenyang 110016,China |
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| Abstract: | 2,5-bihydrazino-1,3,4-thiadiazole was synthesized by the reaction of 2,5-bimer capto-1,3,4-thiadiazloe with hydrazine hydrate and reacted with p-ethoxy benzopyl chloride to produce 2,5-biacylhydrazino-1,3,4-thiadiazole,which was further cycled by POCl3 as cyclization agent to produce 3,6-bi-p-ethoxy-phenyl-1,2,4-triazolo-1,2,4-taiazolo-1,3,4-thiadiazole derivatives.The synthesized compound hasn't been reported,and its structure is confirmed by elemental analysis,I.R spectrum,1H NMR spectrum and MS. |
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| Keywords: | POCl3 |
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