| 有机溶质在含盐固定液中保留参数变化规律的研究——(Ⅱ)溶质——盐存在特殊相互作用的体系 |
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| 引用本文： | 白同春,卢锦梭.有机溶质在含盐固定液中保留参数变化规律的研究——(Ⅱ)溶质——盐存在特殊相互作用的体系[J].河南师范大学学报(自然科学版),1990(3). |
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| 作者姓名： | 白同春 卢锦梭 |
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| 作者单位： | 河南师范大学化学系
(白同春)，河南师范大学化学系(卢锦梭) |
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| 摘 要： | 本文将改进的Scatchard-Hildebrand的溶液理论用于研究在环丁砜含盐溶液中,有机溶质和碱金属盐有特殊相互作用(氢键作用、电荷迁移作用)时,气液色谱保留参数的变化规律。并求得了特殊相互作用平衡常数K_0。
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| 关 键 词： | 氢键作用 电荷迁移作用 气液色谱 非水溶液 |
STUDY ON THE RETENTION BEHAVIOR OF ORGANIC SOLUTES IN STATIONARY SOLUTIONS CONTAINING SALT (Ⅱ) Systems of that there were ungeneral moiecular interactions between solute and salt exist |
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| Bai Tongchun,Lu Jinsuo Chemistry.STUDY ON THE RETENTION BEHAVIOR OF ORGANIC SOLUTES IN STATIONARY SOLUTIONS CONTAINING SALT (Ⅱ) Systems of that there were ungeneral moiecular interactions between solute and salt exist[J].Journal of Henan Normal University(Natural Science),1990(3). |
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| Authors: | Bai Tongchun Lu Jinsuo Chemistry |
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| Institution: | Bai Tongchun;Lu Jinsuo Chemistry Department |
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| Abstract: | The modified Scatchard -- Hildebrand s solution theory has been used to study the GLC retention behavior of or-gunic solutes in stationary solutions containing salt, which take sulfolane as solvent. In these solutions, some ungener-al molecular interactions between solute and salt exist, such as H--bond interaction, charge transfer interaction. The e-quilibrium constants K. of these interactions have been obtained by GLC. |
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| Keywords: | H-bond interaction charge transfer interaction gas liquid chromatography nonaqueous sloution |
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