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| 四氮杂大环-N-二乙酸与Zn(Ⅱ)、Cd(Ⅱ)、Hg(Ⅱ)配合物的合成及表征 | |
| 引用本文： | 陈礼勤，倪诗圣，徐济德，汪国建. 四氮杂大环-N-二乙酸与Zn(Ⅱ)、Cd(Ⅱ)、Hg(Ⅱ)配合物的合成及表征[J]. 安徽大学学报(自然科学版), 1990, 0(4) |
| 作者姓名： | 陈礼勤，倪诗圣，徐济德，汪国建 |
| 作者单位： | 安徽大学化学系，安徽大学化学系，安徽大学化学系，安徽大学化学系 八七届大学生 |
| 摘 要： | 本文报道在水溶液中合成的三种四氮杂大环-N-二乙酸(H_2L~1,H_2L~2和 H_2L~3)与Zn(Ⅱ),Cd(Ⅱ),Hg(Ⅱ)的固体配合物,用元素分析、电导测定及红外光谱对其组成进行了确定。H_2L~1、H_2L~2与三种金属离子分别形成组成为 ZnL·2HCl·nH_2O,Cd(H_2L)·2HCl·Cl_2·nH_2O 和 Hg_2(H_2L)·Cl_4·nH_2O 的配合物。H_2L~3与三种金属离子形成组成为 M_2L·Cl_2·nH_2O 的配合物。根据这些结果提出了这些配合物的可能结构。 |
| 关 键 词： | N-二乙酸四氮杂大环 配合物 锌 镉 汞 |
Synthesis and Characterization of Coordination Compounds of Three Kinds of Tetraazamacrocycle-N-diacetic Acids with Zn(Ⅱ),Cd(Ⅱ),Hg(Ⅱ) |
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| Chen Liqin Ni Shisheng Xu Jide Wang Guojian. Synthesis and Characterization of Coordination Compounds of Three Kinds of Tetraazamacrocycle-N-diacetic Acids with Zn(Ⅱ),Cd(Ⅱ),Hg(Ⅱ)[J]. Journal of Anhui University(Natural Sciences), 1990, 0(4) | |
| Authors: | Chen Liqin Ni Shisheng Xu Jide Wang Guojian |
| Affiliation: | Chen Liqin Ni Shisheng Xu Jide Wang Guojian |
| Abstract: | The coordination compounds of three kinds of tetraazamacrocycle-N- diacetic acids(H_2L~1,H_2L~2,H_2L~3)with Zn(Ⅱ),Cd(Ⅱ) and Hg(Ⅱ)have been synthesized in water sojutions and characterized by elemental analyses,conductivity measurements and IR spectra.The complexes formed by H_2L~1 and H_2L~2 have the stoichiometries of ZnL.2HCl.nH·O,Cd (H_2L).2HCl·Cl_2·nH_2O and Hg_2(H_2L)·Cl_4·nH_2O respectively.The complexes formed by H_2L~3 have the stoichiometries of M_2L·Cl_2·nH_2O. According to the results,tentative structures for these species are proposed. |
| Keywords: | tetraazamacrocycle-N-diacetic acids coordination compounds zinc cadmium mercury |
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