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| 2，3，4，6-四-O-乙酰基书-β-吡喃葡萄糖基异硫氰酸酯合成方法的改进 | |
| 引用本文： | 蔡媛媛,杨思举,赵广凯,赵永德,霍萃萌.2，3，4，6-四-O-乙酰基书-β-吡喃葡萄糖基异硫氰酸酯合成方法的改进[J].河南科学,2009,27(9):1061-1063. |
| 作者姓名： | 蔡媛媛 杨思举 赵广凯 赵永德 霍萃萌 |
| 作者单位： | 1. 河南工业大学,化学化工学院,郑州,450001;河南省科学院,化学研究所,郑州,450002 2. 河南省科学院,化学研究所,郑州,450002;河南大学,化学化工学院,河南,开封,475004 3. 河南省科学院,化学研究所,郑州,450002 |
| 摘 要： | 以葡萄糖为原料经过乙酰化、硫氰化二步反应合成2，3，4，6-四-O-乙酰基-β-D-吡喃葡萄糖基异硫氰酸酯（GITC）．使用重结晶替代柱层析纯化方法，方法操作简便、收率高．并用IR和NMR对其进行了结构确认． |
| 关 键 词： | 葡萄糖 异硫氰酸酯 重结晶 |
Synthesis and Application of 2, 3,4, 6-Tetra-O-acetyl-β-D-glycosyl Isothiocyanate |
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| Cai Yuanyuan,Yang Siju,Zhao Guangkai,Zhao Yongde,Huo Cuimeng.Synthesis and Application of 2, 3,4, 6-Tetra-O-acetyl-β-D-glycosyl Isothiocyanate[J].Henan Science,2009,27(9):1061-1063. | |
| Authors: | Cai Yuanyuan Yang Siju Zhao Guangkai Zhao Yongde Huo Cuimeng |
| Institution: | 1. College of Chemistry and Chemical Engineering;Henan University of Technology;Zhengzhou 450001;China;2. Institute of Chemistry;Henan Academy of Sciences;Zhengzhou 450002;3. College of Chemistry and Chemical Engineering;Henan University;Kaifeng 475004;Henan China |
| Abstract: | 2,3,4,6-Tetra-O-acetyl-β-D-glycosyl isothiocyanate was synthesized using α-D-glucose as the starting material through two step reactions. The purification method is recrystallization. And the structures of the title compounds were confirmed by IR,and 1H-NMR,13C-NMR spectra. The method compares traditional methods with mild reaction conditions,easy purification and higher yield. |
| Keywords: | carbohydrates isothiocyanate catalysis |
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