| 混合配体稀土三元配合物的研究V．吲哚3－丙酸邻菲罗啉稀土三元配合物的合成及性质 |
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| 引用本文： | 赵秀媛,陈忠林,王流芳,吴集贵.混合配体稀土三元配合物的研究V．吲哚3－丙酸邻菲罗啉稀土三元配合物的合成及性质[J].哈尔滨师范大学自然科学学报,1994(2). |
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| 作者姓名： | 赵秀媛 陈忠林 王流芳 吴集贵 |
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| 作者单位： | 哈尔滨建筑工程学院，兰州大学 |
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| 摘 要： | 本文报道首次合成了１５种稀土三元配合物，经过元素与化学分析，确定配合物组成为：ＬｎＰ３Ｐｈｅｎ（Ｌｎ为稀土离子，Ｐ为吲哚－３－丙酸根，Ｐｈｅｎ为邻菲啉），通过化学分析、红外光谱、热谱、紫外光谱．ＨＮＭＲ谱、荧光光谱．Ｘ射线粉末衍射和Ｘ光光电子能谱等方法对新合成三元配合物的结构及性质进行了研究．
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| 关 键 词： | 稀土 三元配合物 邻菲啰啉吲哚－3－丙酸 合成 |
STUDIES ON TERNARY COMPLEXES OF RARE ELEMENTS V. SYNTHESIS,CHARACTERIZATION OF INDOLE-3 PROPIONIC ACID 1,10 -PHENANTHROLINERARE EARTH TERNARY COMPLEXES |
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| Zhao Xiuyuan.STUDIES ON TERNARY COMPLEXES OF RARE ELEMENTS V. SYNTHESIS,CHARACTERIZATION OF INDOLE-3 PROPIONIC ACID 1,10 -PHENANTHROLINERARE EARTH TERNARY COMPLEXES[J].Natural Science Journal of Harbin Normal University,1994(2). |
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| Authors: | Zhao Xiuyuan |
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| Institution: | Zhao Xiuyuan (Harbin Architectural and Civil Enginering Institute)Chen Zhonglin;Wang Liufang; Wu Jigui (Lanzhou University Lanzou 73000) |
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| Abstract: | In this paper we have prepared 15 new ternary Complexes of Rare Earth with indole-3-propionic acid and 1,10- phenanthroline in methanol media, a general formula of the complexes is LnP3 Phen (Ln =Rare Earth ions, P = indole - 3 -propionic acid, Phen= 1,10-phenanthroline).The composition and structure of the prepared compounds have been determined by methods of chemical analyses, element analyses, IR. UV, TG curves, X-ray diffraction, IHNMR, fluorescence spectra and XPS. Some physical and chemical properties of the compounds have been investigated. |
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| Keywords: | Rare earth Ternary complexes 1 10-Phenanthroline Indole-3 -propionic acid Synthesis |
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