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阳离子表面活性剂胶束的增溶过程及其微乳液相图研究
引用本文:李干佐,郝树萱,李英,宋良汉,范爱虎.阳离子表面活性剂胶束的增溶过程及其微乳液相图研究[J].山东大学学报(理学版),1994(4).
作者姓名:李干佐  郝树萱  李英  宋良汉  范爱虎
作者单位:山西大学化学系
摘    要:运用NMR方法,研究了阳离子表面活性剂CTAB形成的胶束对间二甲苯和苯甲醇的增溶过程,并比较了两者的增溶位置和增溶过程的异同.同时在十六烷基三甲基溴化铵(CTAB)/水/辛烷体系中,研究了不同分子量的醇对其微乳液形成的影响.当醇的分子量改变时,通过测定CTAB/水/油/醇体系的四组分相图,得到微乳液的类型和区域面积等变化规律.

关 键 词:阳离子表面活性剂  胶束  微乳液  增溶过程  相图

SOLUBILIZATION OF MICELL AND DIAGRAM OF MICROEMULSION FOR CATIONIC SURFACTANT
Li Ganzuo,Hao Shuxuan,Li Ying.SOLUBILIZATION OF MICELL AND DIAGRAM OF MICROEMULSION FOR CATIONIC SURFACTANT[J].Journal of Shandong University,1994(4).
Authors:Li Ganzuo  Hao Shuxuan  Li Ying
Abstract:The effect of various kinds of alcohols on the forming of microemulsions in CTAB/H2O/octane/alcohol systems was studied. While the molecular weights of alcohols were changed, from investigating the pseudoternary phase diagrams, laws about the variation of the kinds and areas of microemulsions with alcohol molecular weights have been gotten. And NMR method was used to determine the solubilizated location of benzyl alcohol (or mdimethyl benzene) in CTAB/D2O / micellarsystem, and the former laws were verified.
Keywords:cationic surfactant  micelle  microemulsion  solubilizated process  phase diagram  
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