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腐殖酸包覆Fe_3O_4纳米粒子类Fenton催化降解亚甲基蓝
引用本文:杜思南,秦振立,罗阳,廖芝建,左芳,刘东.腐殖酸包覆Fe_3O_4纳米粒子类Fenton催化降解亚甲基蓝[J].西南民族大学学报(自然科学版),2016,42(3):285-292.
作者姓名:杜思南  秦振立  罗阳  廖芝建  左芳  刘东
作者单位:西南民族大学化学与环境保护工程学院,西南民族大学化学与环境保护工程学院,西南民族大学化学与环境保护工程学院,西南民族大学化学与环境保护工程学院,西南民族大学化学与环境保护工程学院,西南民族大学化学与环境保护工程学院
基金项目:国家自然科学基金(51273220),四川省科技支撑计划项目(2014GZ0012)
摘    要:采用共沉淀法制备腐殖酸包覆的磁性四氧化三铁纳米粒子(HA@Fe_3O_4)并将其用于类Fenton体系催化降解亚甲基蓝(MB).通过透射电子显微镜(TEM)、动态光散射(DLS)、X射线衍射仪(XRD)、傅里叶变换红外光谱(FT-IR)对样品的形貌、结构及成分进行表征.比较HA包覆前后Fe_3O_4纳米粒子的催化效果,考察HA@Fe_3O_4催化剂用量、H_2O_2浓度等因素对降解效率的影响.结果表明HA的包覆可以显著提高MB的降解效率.

关 键 词:腐殖酸  亚甲基蓝  磁性纳米粒子  Fenton
收稿时间:2016/3/16 0:00:00
修稿时间:2016/4/8 0:00:00

Removal of methylene blue by humic acid coated Fe3O4 magnetic nanoparticles as Fenton-like catalyst
Du Sinan,Qin Zhenli,Luo Yang,Liao Zhijian,Zuo Fang and Liu Dong.Removal of methylene blue by humic acid coated Fe3O4 magnetic nanoparticles as Fenton-like catalyst[J].Journal of Southwest University for Nationalities(Natural Science Edition),2016,42(3):285-292.
Authors:Du Sinan  Qin Zhenli  Luo Yang  Liao Zhijian  Zuo Fang and Liu Dong
Institution:Southwest University for Nationalities,Southwest University for Nationalities,Southwest University for Nationalities,Southwest University for Nationalities,Southwest University for Nationalities and Southwest University for Nationalities
Abstract:Humic acid coated Fe3O4 magnetic nanoparticles (HA@Fe3O4) were prepared by coprecipitation method. The morphology, structure and composition of the magnetic nanoparticles were characterized by transmission electron microscope (TEM), dynamic light scattering (DLS), X-ray diffraction (XRD), and Fourier-transform infrared (FT-IR) spectra. The effects of catalyst addition and hydrogen peroxide (H2O2) concentration on the degradation efficiency were investigated by choosing the methylene blue (MB) as the degradation model and HA@Fe3O4 as catalysts. The result showed that the coating of HA obviously accelerated the degradation rate of MB.
Keywords:humic acid  methylene blue  magnetic nanoparticle  Fenton
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