| 3,5-二溴水杨醛缩邻苯二胺及其配合物的合成与谱学性质 |
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| 引用本文： | 吴宇,谢斌,邹立科,赖川,赵兴秀,蒋聪.3,5-二溴水杨醛缩邻苯二胺及其配合物的合成与谱学性质[J].四川理工学院学报(自然科学版),2009,22(3):54-56. |
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| 作者姓名： | 吴宇 谢斌 邹立科 赖川 赵兴秀 蒋聪 |
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| 作者单位： | 1. 四川理工学院化学与制药工程学院,四川,自贡,643000
2. 四川理工学院生物工程学院,四川,自贡,643000 |
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| 基金项目： | 四川省教育厅科学研究项目，自贡市科技局科研项目，四川理工学院科研项目 |
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| 摘 要： | 合成了3,5-二溴水杨醛缩邻苯二胺配体H2L(L=C20H10N2O2Br4)及其铜(II)、镍(II)的配合物ML.Py(M为Cu和Ni;Py为吡啶)和锌的配合物ZnL.Py].DMF,并用元素分析、红外光谱、紫外-可见光谱对它们进行了表征,同时用质谱、核磁共振谱对配体进行了表征。研究结果表明配合物为五配位,吡啶分子参与了配位。
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| 关 键 词： | 3 5-二溴水杨醛缩邻苯二胺 配合物 光谱 表征 |
Synthesis and Spectroscopic Properties of N,N'-o-phenylenebis(3,5-dibromosalicylideneimine) and Its Complexes |
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| WU Yu,XIE Bin,ZOU Li-ke,LAI Chuan,ZHAO Xing-xiu,JIANG Cong.Synthesis and Spectroscopic Properties of N,N'-o-phenylenebis(3,5-dibromosalicylideneimine) and Its Complexes[J].Journal of Sichuan University of Science & Engineering:Natural Science Editton,2009,22(3):54-56. |
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| Authors: | WU Yu XIE Bin ZOU Li-ke LAI Chuan ZHAO Xing-xiu JIANG Cong |
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| Institution: | 1.School of Chemical and Pharmaceutical Engineering;Sichuan University of Science & Engineering;Zigong 643000;China;2.School of Biotechnology Engineering;China |
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| Abstract: | The complexes of zinc(II),copper(II) or nickel(II) with N,N'-o-phenylenebis(3,5-dibromosalicylideneimine),ML·Py(M=Cu(II) or Ni(II),L=C20H10N2O2Br4) orZnL·Py]·DMF,were synthesized in DMF and Pyridine solution.The complexes were characterized by elemental analysis,IR,UV-vis,while the ligand was characterized by MS and HNMR spectra.The results show the complexes were five-coordinated forms which included the molecule Py. |
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| Keywords: | N N'-o-phenylenebis-(3 5-dibromosalicylideneimine) complexes spectroscopy characterization |
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