| 有机化合物选择性氧化的研究——三氧化铬盐酸乙二胺盐酸盐的制备及对醇类的氧化 |
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| 引用本文： | 魏章申,石启增,蔡昆. 有机化合物选择性氧化的研究——三氧化铬盐酸乙二胺盐酸盐的制备及对醇类的氧化[J]. 河南师范大学学报(自然科学版), 1992, 0(2) |
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| 作者姓名： | 魏章申 石启增 蔡昆 |
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| 作者单位： | 河南师范大学化学系，河南师范大学化学系，河南师范大学化学系 |
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| 摘 要： | 包括三氧化铬盐酸乙二胺盐酸盐的制备和它在DMF中对醇类的氧化性能,发现作为一种新的、温和的氧化剂,它仅能氧化苄醇、烯丙醇和环醇类生成相应的羰基化合物,对其它的链状饱和醇则不氧化。
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| 关 键 词： | 三氧化铬盐酸乙二胺盐酸盐 选择性氧化 醇 |
STUDY ON SELECTIVE OXIDATION OF ORGANIC COMPOUNDS——The Preparation of Ethylene Diamone Hydrochloride Chlorochromate and Selective Oxidation of Alcohols with It |
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| Wei Zhangshen,Shi Qizheng,Cai Kun. STUDY ON SELECTIVE OXIDATION OF ORGANIC COMPOUNDS——The Preparation of Ethylene Diamone Hydrochloride Chlorochromate and Selective Oxidation of Alcohols with It[J]. Journal of Henan Normal University(Natural Science), 1992, 0(2) |
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| Authors: | Wei Zhangshen Shi Qizheng Cai Kun |
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| Affiliation: | Wei Zhangshen;Shi Qizheng;Cai Kun Department of Chemistry |
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| Abstract: | This paper consists of synthesis of cthlene diamine hydrochloride chlorchromatc (EDHCC) and its application for oxidation of alcohols. EDHCC, a new mild oxidizing agent, is found to oxidize of bcnzylic, allylic and cyclic alcohols to the corresponding carbonyl compounds in a excellent yields. But it is unablc to oxidize of other satruated alcohols in the same conditions. |
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| Keywords: | ethylene diamine hydrochloride chlorochromate selective oxidation alcohol |
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