| 化学偶联反应条件探析 |
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| 引用本文： | 张维冰,吴也平,卢英华.化学偶联反应条件探析[J].高师理科学刊,1992(3). |
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| 作者姓名： | 张维冰 吴也平 卢英华 |
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| 作者单位： | 齐齐哈尔轻工学院
(张维冰，吴也平)，齐齐哈尔轻工学院(卢英华) |
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| 摘 要： | 本文对化学偶联反应的发生条件加以详细探析,发现化学偶联反应的发生不仅需满足已知的特定热力学条件,而且也应满足一定的动力学条件.若只有两个基元反应偶联,在弛豫时间里,该动力学条件:JT_1A_1~2—JT_2A_2~2>0,这一结果也说明了文献3]中的结论存在一定的片面性.
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| 关 键 词： | 偶联反应 化学势 质量作用定律 |
Investigation into Conditions of Chemical Coupled Reaction |
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| Zhang Weibing Wu Yeping Lu Yinghua.Investigation into Conditions of Chemical Coupled Reaction[J].Journal of Science of Teachers＇College and University,1992(3). |
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| Authors: | Zhang Weibing Wu Yeping Lu Yinghua |
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| Institution: | Qiqihar Light Industry Institute |
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| Abstract: | In this paper are investigated conditions of chemical coupled
reactions, and is discovered that not only some known thermodynamics
conditions, but also a dynamics condition must be satisfied. To two
elementary reactions coupling, the dynamics condition is A12Jr1 -A22Jr2>0, This result shows that Li' s result did not seem suitable. |
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| Keywords: | Coupled reaction Chemical potential Mass action law |
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